A 2-D CdI2 coordination network with 7-oxabicyclo[2.2.1]-5-heptene-2,3-dicarboxylate: synthesis, crystal structure, and luminescent properties

被引：9

作者：

Hu, Min ^{[1
]}

Chen, Min ^{[1
]}

Yang, Xiao-Gang ^{[1
]}

Fang, Shao-Ming ^{[1
]}

Liu, Chun-Sen ^{[1
]}

机构：

[1] Zhengzhou Univ Light Ind, Henan Prov Key Lab Surface & Interface Sci, Zhengzhou 450002, Henan, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2011年 / 64卷 / 22期

关键词：

Cd-II complex; 7-Oxabicyclo[2.2.1]-5-heptene-2,3-dicarboxylic anhydride; Crystal structure; Topology; Luminescence; METAL-ORGANIC FRAMEWORKS; HYDROTHERMAL SYNTHESIS; MOLECULAR TECTONICS; MIXED-LIGANDS; CD(II); COMPLEXES; POLYMERS; CLUSTER; ACID; MOFS;

D O I：

10.1080/00958972.2011.634004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The in situ reaction of Cd(ClO4)(2)center dot 6H(2)O with 7-oxabicyclo[2.2.1]-5-heptene-2,3-dicarboxylic anhydride in the presence of lithium hydroxide affords a 2-D Cd-II coordination polymer, [Cd(L)(H2O)](infinity) (1) (L = 7-oxabicyclo[2.2.1]-5-heptene-2,3-dicarboxylate), which exhibits an unusual (3,6)-connected (4(6)center dot 6(6)center dot 8(3))(4(3))(2) CdI2-type topology. The luminescent and thermal properties of 1 were investigated.

引用

页码：3928 / 3937

页数：10

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