Effect of nano-TiO2 particles size on the corrosion resistance of alkyd coating

被引:73
作者
Deyab, M. A. [1 ]
Keera, S. T. [1 ]
机构
[1] Egyptian Petr Res Inst, Cairo, Egypt
关键词
Non-crystalline materials; Coatings; Corrosion; Electrochemical techniques; CARBON-STEEL; STAINLESS-STEEL; ACID-SOLUTION; HYDROCHLORIC-ACID; MILD-STEEL; BEHAVIOR; INHIBITION; ADSORPTION; NANOCOMPOSITE; SURFACTANT;
D O I
10.1016/j.matchemphys.2014.03.045
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The coating system containing various sizes (similar to 10, 50, 100, 150 nm) of nano-TiO2 were prepared and investigated for corrosion protection of carbon steel in 1.0 M H2SO4 using polarization, EIS and transmission electron microscopy (TEM) techniques. It was found that nano-TiO2 particles improved the corrosion resistance of alkyd coatings. The corrosion resistance occurs via physical adhesion on the metal surface. O-2 and H2O permeability of coating decreased with decrease in the nano-TiO2 size. The inhibition efficiency was found to increase with decreasing the size of nano-TiO2 and with decreasing the temperature. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:406 / 411
页数:6
相关论文
共 29 条
[1]   Degradation and stabilisation of polymers and coatings: nano versus pigmentary titania particles [J].
Allen, NS ;
Edge, M ;
Ortega, A ;
Sandoval, G ;
Liauw, CM ;
Verran, J ;
Stratton, J ;
McIntyre, RB .
POLYMER DEGRADATION AND STABILITY, 2004, 85 (03) :927-946
[2]  
[Anonymous], 1981, ELECTROCHIM ACTA, DOI DOI 10.1016/0013-4686(81)85107-9
[3]  
[Anonymous], D709105 ASTM, V6.1, P1
[4]  
Ashassi-Sorkhabi H, 2006, INT J ELECTROCHEM SC, V1, P92
[5]   SOL-GEL TIO2-SIO2 FILMS AS PROTECTIVE COATINGS AGAINST CORROSION OF 316L STAINLESS-STEEL IN H2SO4 SOLUTIONS [J].
ATIK, M ;
NETO, PD ;
AEGERTER, MA ;
AVACA, LA .
JOURNAL OF APPLIED ELECTROCHEMISTRY, 1995, 25 (02) :142-148
[6]   PROTECTIVE TIO2-SIO2 COATINGS ON STAINLESS-STEEL SHEETS PREPARED BY DIP-COATING [J].
ATIK, M ;
ZARZYCKI, J .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1994, 13 (17) :1301-1304
[7]   Enhancing coating functionality using nanoscience and nanotechnology [J].
Baer, DR ;
Burrows, PE ;
El-Azab, AA .
PROGRESS IN ORGANIC COATINGS, 2003, 47 (3-4) :342-356
[8]   An efficient protection of stainless steel against corrosion:: Combination of a conversion layer and titanium dioxide deposit [J].
Bamoulid, L. ;
Maurette, M. -T. ;
De Caro, D. ;
Guenbour, A. ;
Ben Bachir, A. ;
Aries, L. ;
El Hajjaji, S. ;
Benoit-Marquie, F. ;
Ansart, F. .
SURFACE & COATINGS TECHNOLOGY, 2008, 202 (20) :5020-5026
[9]   Thermodynamic characterization of metal dissolution and inhibitor adsorption processes in mild steel/2,5-bis(n-thienyl)-1,3,4-thiadiazoles/hydrochloric acid system [J].
Bentiss, F ;
Lebrini, M ;
Lagrenée, M .
CORROSION SCIENCE, 2005, 47 (12) :2915-2931
[10]  
Bockris J., 1977, Modern Electrochemistry, V2