Synthesis of Ni2P/Zn3In2S6 hierarchical heterostructure for improving photocatalytic H2 evolution

被引:43
作者
Chu, Li-Li [1 ]
机构
[1] Xinxiang Univ, Sch Life Sci & Technol, Xinxiang 453003, Henan, Peoples R China
关键词
Photocatalysis; Zn3In2S6; Ni2P; Photocatalytic H-2 evolution; Nanocomposite; AROMATIC ALCOHOLS; NI2P COCATALYST; HYDROGEN; SEPARATION; OXIDATION; CARBON; SYSTEM; OXYGEN;
D O I
10.1016/j.catcom.2019.05.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
2D-3D noble-metal-free Ni2P/Zn3In2S6 hierarchical composites were fabricated firstly by the hydrothermal method and characterized by the relative techniques. The average H-2 evolution rate over the optimized Ni2P/Zn3In2S6 under simulated sunlight can reach up to 6.4 mmol g(-1) h(-1), which is about 3.4 and 2.6 times higher than that of pure Zn3In2S6 and Pt/Zn3In2S6 hybrid. The excellent photocatalytic performance can be attributed to the interaction between the well-dispersed ultrafine Ni2P cocatalyst and the 2D-3D Zn3In2S6 hierarchical structure, which contributes to the separation and transportation of the photoinduced charge carriers.
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页数:4
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