Enantioselective alpha hydroxylation of carboxylic acids with molecular oxygen catalyzed by the alpha oxidation enzyme system of young pea leaves (Pisum sativum): A substrate selectivity study

被引：24

作者：

Adam, W ^{[1
]}

Lazarus, M ^{[1
]}

SahaMoller, CR ^{[1
]}

Schreier, P ^{[1
]}

机构：

[1] UNIV WURZBURG,INST PHARM & FOOD CHEM,D-97074 WURZBURG,GERMANY

来源：

TETRAHEDRON-ASYMMETRY | 1996年 / 7卷 / 08期

关键词：

D O I：

10.1016/0957-4166(96)00283-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The substrate selectivity of the a oxidation of carboxylic acids I by crude homogenate of young pea leaves was investigated. Saturated fatty acids with 7 to 16 carbon atoms and oleic acid were transformed to the enantiomerically pure (R)-2-hydroxy acids 2 in the presence of molecular oxygen. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：2287 / 2292

页数：6

共 3 条

[1] α hydroxylation of carboxylic acids with molecular oxygen catalyzed by the α oxidase of peas (Pisum sativum):: A novel biocatalytic synthesis of enantiomerically pure (R)-2-hydroxy acids
Adam, W
Boland, W
Hartmann-Schreier, J
Humpf, HU
Lazarus, M
Saffert, A
Saha-Moller, CR
Schreier, P
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (43) : 11044 - 11048
[2] THE ALPHA-OXIDASE SYSTEM OF YOUNG PEA LEAVES (PISUM-SATIVUM) AS GENERATOR OF ELECTRONICALLY EXCITED-STATES - EXCITATION IN THE DARK UNDER NATURAL CONDITIONS
SALIMHANNA, M
CAMPA, A
CILENTO, G
PHOTOCHEMISTRY AND PHOTOBIOLOGY, 1987, 45 (06) : 849 - 854
[3] METAL-ION CATALYZED OXIDATION OF STEROIDS .1. 15ALPHA-HYDROXYLATION OF DEOXYCHOLIC ACID IN AQUEOUS-SOLUTION BY FERROUS ION-MOLECULAR OXYGEN SYSTEM
KIMURA, M
KAWATA, M
TOHMA, M
SAWAYA, T
YAMAZAKI, K
FUJINO, A
CHEMICAL & PHARMACEUTICAL BULLETIN, 1972, 20 (09) : 1883 - +

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