trans-diacetonitrilebis(di-2-pyridyl sulfide-N,N′)ruthenium(II) bis(tetrafluoroborate)monohydrate

被引：10

作者：

Bruno, G ^{[1
]}

Nicoló, F ^{[1
]}

Tresoldi, G ^{[1
]}

Lanza, S ^{[1
]}

机构：

[1] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷 / 01期

关键词：

D O I：

10.1107/S0108270101018091

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title complex, [Ru(C10H8N2S)(2)(CH3CN)(2)](BF4)(2).H2O, is the product of the solvolysis of [Ru(dps-N,N)(2) (dps-N,S)](PF6)(2) (dps is di-2-pyridyl sulfide) in the presence of HBF4 in acetone-acetonitrile at room temperature. There are two independent cations, with the Ru atoms on inversion centres; each Ru atom has an octahedral geometry with the dps molecules behaving as N,N'-bidentate ligands and assuming a trans arrangement.

引用

页码：M56 / M58

页数：3

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