Tunability of Band Gaps in Metal-Organic Frameworks

被引：154

作者：

Lin, Chi-Kai ^{[1
,2
]}

Zhao, Dan ^{[1
]}

Gao, Wen-Yang ^{[3
]}

Yang, Zhenzhen ^{[2
]}

Ye, Jingyun ^{[4
]}

Xu, Tao ^{[2
]}

Ge, Qingfeng ^{[4
]}

Ma, Shengqian ^{[1
,3
]}

Liu, Di-Jia ^{[1
]}

机构：

[1] Argonne Natl Lab, Chem Sci & Engn Div, Argonne, IL 60439 USA

[2] No Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA

[3] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[4] So Illinois Univ, Dept Chem & Biochem, Carbondale, IL 62901 USA

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 16期

基金：

美国国家科学基金会;

关键词：

ENERGY-LEVEL ALIGNMENT; ZNO QUANTUM DOTS; METALLOPORPHYRIN FRAMEWORK; OPTICAL-PROPERTIES; ISORETICULAR MOFS; DESIGN; PHOTOLUMINESCENCE; RECOGNITION; CHEMISTRY; PLATFORM;

D O I：

10.1021/ic301189m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The tunability of the band gaps in Zn-based metal-organic frameworks (MOFs) has been experimentally demonstrated via two different approaches: changing the cluster size of the secondary building unit (SBU) or alternating the conjugation of the organic linker.

引用

页码：9039 / 9044

页数：6

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