Multilayered architecture of graphene nanosheets and MnO2 nanowires as an electrode material for high-performance supercapacitors

被引：36

作者：

Wu, Mao-Sung ^{[1
]}

Lin, Chih-Jui ^{[1
]}

Ho, Chia-Ling ^{[1
]}

机构：

[1] Natl Kaohsiung Univ Appl Sci, Dept Chem & Mat Engn, Kaohsiung 807, Taiwan

来源：

ELECTROCHIMICA ACTA | 2012年 / 81卷

关键词：

Graphene; Manganese oxide; Supercapacitor; Electrophoretic deposition; Anodic deposition; ELECTROCHEMICAL PROPERTIES; NANOTUBE HYBRID; COMPOSITES; OXIDE; FILMS; ZNO;

D O I：

10.1016/j.electacta.2012.07.083

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Multilayered graphene/MnO2 nanocomposite electrode prepared by anodic electrodeposition and electrophoresis exhibited superior capacitive behavior compared to the bare MnO2 and graphene electrodes. The multilayered architecture provided both the horizontal and vertical channels for electrolyte access during fast charging and discharging. The graphene layer turned out to play an important role in enhancing the electron conduction in the multilayered architecture. Therefore, the improved electrochemical behavior might result from the significantly improved ion transport and electron conduction in the multilayered architecture of the graphene/MnO2 composite electrode. Furthermore, the MnO2 nanowire layer coated on the graphene layer could significantly suppress the oxygen evolution reaction, broadening the potential window of water stability. (c) 2012 Elsevier Ltd. All rights reserved.

引用

页码：44 / 48

页数：5

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