Synthesis and structure of an aluminum borate chloride consisting of 12-membered borate rings and aluminate clusters

被引：45

作者：

Gao, Wenliang ^{[1
]}

Wang, Yingxia ^{[1
]}

Li, Guobao ^{[1
]}

Liao, Fuhui ^{[1
]}

You, Liping ^{[1
]}

Lin, Jianhua ^{[1
]}

机构：

[1] Peking Univ, Beijing Natl Lab Mol Sci, State Key Lab Rare Earth Mat Chem & Applicat, Coll Chem & Mol Engn, Beijing 100871, Peoples R China

来源：

INORGANIC CHEMISTRY | 2008年 / 47卷 / 16期

关键词：

D O I：

10.1021/ic8010053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new aluminum borate chloride (PKU-8) was synthesized in a flux of boric acid, and the structure was established using powder X-ray diffraction techniques. PKU-8 contains an unusual framework structure of a large cage consisting of 12-membered borate rings [B12O30] and aluminate octahedra clusters [Al7O24].

引用

页码：7080 / 7082

页数：3

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