RuCl3•xH2O:: A novel and efficient catalyst for the facile synthesis of 1,5-benzodiazepines under solvent-free conditions

被引：7
作者：
Suresh [1 ]
Saini, Anil [1 ]
Sandhu, Jagir S. [1 ]
机构：
[1] Punjabi Univ, Dept Chem, Patiala 147002, Punjab, India
来源：
SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 18期
关键词：
1,5-benzodizepines; o-phenylenediamine; ketones; RuCl3 center dot xH(2)O; solvent-free;
D O I：
10.1080/00397910802109273
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1,5-Benzodizepines are synthesized in excellent yields via condensation of o-phenylenediamine with ketones having a hydrogen at the alpha-position. The reaction is performed in solvent-free conditions and 5mol% of RuCl3 center dot xH(2)O is enough to direct the reaction to completion.
引用
收藏
页码：3193 / 3200
页数：8
相关论文
共 50 条
  • [41] Synthesis of new 1,5-diaryl-3-(arylamino)-1H-pyrrol-2(5H)-ones under catalyst-free and solvent-free conditions
    Niknam, Khodabakhsh
    Mojikhalifeh, Sanaz
    [J]. MOLECULAR DIVERSITY, 2014, 18 (01) : 111 - 117
  • [42] Facile and green synthesis of triarylmethanes using silica sulfuric acid as a reusable catalyst under solvent-free conditions
    Mohammadpoor-Baltork, I.
    Moghadam, M.
    Tangestaninejad, S.
    Mirkhani, V.
    Mohammadiannejad-Abbasabadi, K.
    Zolfigol, M. A.
    [J]. COMPTES RENDUS CHIMIE, 2011, 14 (10) : 934 - 943
  • [43] Synthesis of new 1,5-diaryl-3-(arylamino)-1H-pyrrol-2(5H)-ones under catalyst-free and solvent-free conditions
    Khodabakhsh Niknam
    Sanaz Mojikhalifeh
    [J]. Molecular Diversity, 2014, 18 : 111 - 117
  • [44] Facile synthesis of novel dihydroquinoline-3,3-dicarbonitriles in the presence of glacial acetic acid as a catalyst under solvent-free conditions
    Kanaani, Elham
    Nasr-Esfahani, Masoud
    [J]. SYNTHETIC COMMUNICATIONS, 2017, 47 (14) : 1326 - 1331
  • [45] Ni(OAc)2: a highly efficient catalyst for the synthesis of enaminone and enamino ester derivatives under solvent-free conditions
    Liu, Ju-Yan
    Cao, Gai-E
    Xu, Wei
    Cao, Jie
    Wang, Wei-Lu
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2010, 24 (10) : 685 - 691
  • [46] Nanocrystalline MgAl2O4 as an efficient catalyst for one-pot synthesis of multisubstituted imidazoles under solvent-free conditions
    Safari, Javad
    Akbari, Zahra
    Naseh, Simin
    [J]. JOURNAL OF SAUDI CHEMICAL SOCIETY, 2016, 20 : S250 - S255
  • [47] ZrOCl28H2O: An Efficient Catalyst for One-Pot Synthesis of -Amino Phosphonates Under Solvent-Free Conditions
    Bhanushali, Mayur J.
    Nandurkar, Nitin S.
    Jagtap, Sachin R.
    Bhanage, Bhalchandra M.
    [J]. SYNTHETIC COMMUNICATIONS, 2009, 39 (05) : 845 - 859
  • [48] ZrOCl2•8H2O as an efficient and recyclable catalyst for the clean synthesis of xanthenedione derivatives under solvent-free conditions
    Mosaddegh, Elaheh
    Islami, Mohammad Reza
    Hassankhani, Asadollah
    [J]. ARABIAN JOURNAL OF CHEMISTRY, 2012, 5 (01) : 77 - 80
  • [49] Efficient and Facile Synthesis of 3-Amino-1-aryl-9H-fluorene-2,4-dicarbonitrile Under Solvent-Free Conditions
    Rong, Liangce
    Han, Hongxia
    Jiang, Hong
    Tu, Shujiang
    [J]. SYNTHETIC COMMUNICATIONS, 2009, 39 (19) : 3493 - 3499
  • [50] Trifluoroacetate-bonded polyethylene graphene oxide composite as a novel and efficient catalyst for the synthesis of benzimidazoles under solvent-free conditions
    Rostami, Esmael
    Haghayeghi, Seyed Mandi
    [J]. IRANIAN JOURNAL OF CATALYSIS, 2021, 11 (01): : 37 - 48
12345