RuCl3•xH2O:: A novel and efficient catalyst for the facile synthesis of 1,5-benzodiazepines under solvent-free conditions

被引:7
作者
Suresh [1 ]
Saini, Anil [1 ]
Sandhu, Jagir S. [1 ]
机构
[1] Punjabi Univ, Dept Chem, Patiala 147002, Punjab, India
关键词
1,5-benzodizepines; o-phenylenediamine; ketones; RuCl3 center dot xH(2)O; solvent-free;
D O I
10.1080/00397910802109273
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
1,5-Benzodizepines are synthesized in excellent yields via condensation of o-phenylenediamine with ketones having a hydrogen at the alpha-position. The reaction is performed in solvent-free conditions and 5mol% of RuCl3 center dot xH(2)O is enough to direct the reaction to completion.
引用
收藏
页码:3193 / 3200
页数:8
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