RuCl3•xH2O:: A novel and efficient catalyst for the facile synthesis of 1,5-benzodiazepines under solvent-free conditions

被引：7
|
作者：
Suresh [1 ]
Saini, Anil [1 ]
Sandhu, Jagir S. [1 ]
机构：
[1] Punjabi Univ, Dept Chem, Patiala 147002, Punjab, India
来源：
SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 18期
关键词：
1,5-benzodizepines; o-phenylenediamine; ketones; RuCl3 center dot xH(2)O; solvent-free;
D O I：
10.1080/00397910802109273
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
1,5-Benzodizepines are synthesized in excellent yields via condensation of o-phenylenediamine with ketones having a hydrogen at the alpha-position. The reaction is performed in solvent-free conditions and 5mol% of RuCl3 center dot xH(2)O is enough to direct the reaction to completion.
引用
收藏
页码：3193 / 3200
页数：8
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