Organic Photoredox Catalysis

被引:4665
|
作者
Romero, Nathan A. [1 ]
Nicewicz, David A. [1 ]
机构
[1] Univ North Carolina Chapel Hill, Dept Chem, Chapel Hill, NC 27599 USA
关键词
PHOTOINDUCED ELECTRON-TRANSFER; AEROBIC OXIDATIVE CYCLIZATION; ANTI-MARKOVNIKOV ADDITION; TRIPLET EXCITED-STATE; DIELS-ALDER REACTION; C-H ARYLATION; CYCLOADDITION/OXIDATIVE AROMATIZATION SEQUENCE; ENANTIOSELECTIVE BIOMIMETIC CYCLIZATION; RADICAL-CROSSOVER CYCLOADDITIONS; NUCLEOPHILE-OLEFIN COMBINATION;
D O I
10.1021/acs.chemrev.6b00057
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic transformations with a range of applications. This Overview is arranged by catalyst class where the photophysics and electrochemical characteristics of each is,discussed to underscore the differences and advantages to each type of single electron redox agent. We highlight both net reductive and oxidative as well as redox neutral transformations that can be accomplished using purely organic photoredoxactive catalysts. An overview of the basic photophysics and electron transfer theory is presented in order to provide a comprehensive guide for employing this class Of catalysts in photoredox manifolds.
引用
收藏
页码:10075 / 10166
页数:92
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