Ferrocenyl-substituted low-coordinated heavier group 14 elements

被引：13

作者：

Sasamori, Takahiro ^{[1
]}

机构：

[1] Nagoya City Univ, Grad Sch Sci, Mizuho Ku, Yamanohata 1,Mizuho Cho, Nagoya, Aichi 4678501, Japan

来源：

DALTON TRANSACTIONS | 2020年 / 49卷 / 24期

关键词：

MAIN-GROUP ELEMENTS; DOUBLE-BONDS; STRUCTURAL-CHARACTERIZATION; SILICON-COMPOUNDS; SOLID-STATE; ANALOGS; ANION; ACTIVATION; PRECURSORS; REACTIVITY;

D O I：

10.1039/d0dt01426e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several examples of stable low-coordinated species of heavier group 14 elements (Si, Ge, Sb, Pb) such as divalent species and multiple-bond compounds have been reported. With the goal in mind to create unprecedented low-coordinated species of heavier group 14 elements that exhibit considerably increased redox stability, ferrocenyl (Fc)-substituted low-coordinated species of heavier group 14 elements were designed. In this short account article, recent progress on the synthesis of Fc-based low-coordinated species of heavier group 14 elements is summarized.

引用

页码：8029 / 8035

页数：7

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