Responsive Polymers as Smart Nanomaterials Enable Diverse Applications

被引：39

作者：

Zhao, Jing ^{[1
,2
]}

Lee, Victoria E. ^{[3
,4
]}

Liu, Rui ^{[1
,2
]}

Priestley, Rodney D. ^{[3
,4
]}

机构：

[1] Tongji Univ, Key Lab Adv Civil Engn Mat, Sch Mat Sci & Engn, Minist Educ, Shanghai 201804, Peoples R China

[2] Tongji Univ, Inst Adv Study, Shanghai 201804, Peoples R China

[3] Princeton Univ, Dept Chem & Biol Engn, Princeton, NJ 08544 USA

[4] Princeton Univ, Princeton Inst Sci & Technol Mat, Princeton, NJ 08544 USA

来源：

ANNUAL REVIEW OF CHEMICAL AND BIOMOLECULAR ENGINEERING, VOL 10 | 2019年 / 10卷

基金：

美国国家科学基金会; 中国国家自然科学基金;

关键词：

polymeric nanoparticles; stimuli-responsive polymers; self-assembly; smart materials; BLOCK-COPOLYMER VESICLES; DRUG-DELIVERY; SENSITIVE HYDROGELS; POLY(ACRYLIC ACID); POTENTIAL CHANGES; HECK REACTIONS; PH; TEMPERATURE; MEMBRANES; POLYMERIZATION;

D O I：

10.1146/annurev-chembioeng-060718-030155

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Responsive polymers undergo reversible or irreversible physical or chemical modifications in response to a change in environment or stimulus, e.g., temperature, pH, light, and magnetic or electric fields. Polymeric nanoparticles (NPs), which constitute a diverse set of morphologies, including micelles, vesicles, and core-shell geometries, have been successfully prepared from responsive polymers and have shown great promise in applications ranging from drug delivery to catalysis. In this review, we summarize pH, thermo-, photo-, and enzymatic responsiveness for a selection of polymers. We then discuss the formation of NPs made from responsive polymers. Finally, we highlight how NPs and other nanomaterials are enabling a wide range of smart applications with improved efficiency, as well as improved sustainability and recyclability of polymeric systems.

引用

页码：361 / 382

页数：22