PPH dendrimers grafted on silica nanoparticles: surface chemistry, characterization, silver colloids hosting and antibacterial activity

被引:17
作者
Hameau, Aurelien [1 ,2 ]
Colliere, Vincent [1 ,2 ]
Grimoud, Julien [3 ]
Fau, Pierre [1 ,2 ]
Roques, Christine [3 ]
Caminade, Anne-Marie [1 ,2 ]
Turrin, Cedric-Olivier [1 ,2 ]
机构
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse 4, France
[2] Univ Toulouse, UPS, INPT, F-31077 Toulouse 4, France
[3] UPS, Fac Pharm, Lab Genie Chim, UMR 5503, F-31062 Toulouse 9, France
关键词
PHOSPHORUS-CONTAINING DENDRIMERS; MICROSPHERES; NANOCLUSTERS; DERIVATIVES; POLYMER; AGENTS; CORE; AG;
D O I
10.1039/c3ra43348j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polyphosphorhydrazone (PPH) dendrimers have been grafted on silica nanoparticles, and the surface functions of the dendrimers have been derivatized to phosphonates with lateral poly(ethyleneglycol) (PEG) chains. All materials have been thoroughly characterized by MAS NMR, FT-IR, electron microscopy, TGA and elemental analysis. These materials successfully hosted silver and silver oxide nanoparticles. The resulting composites exhibit antibacterial activity.
引用
收藏
页码:19015 / 19026
页数:12
相关论文
共 40 条
[1]   Bronsted acid-mediated synthesis of α-amino phosphonates under solvent-free conditions [J].
Akiyama, T ;
Sanada, M ;
Fuchibe, K .
SYNLETT, 2003, (10) :1463-1464
[2]   Carbonylation reactions of iodoarenes with PAMAM dendrimer-palladium catalysts immobilized on silica [J].
Antebi, S ;
Arya, P ;
Manzer, LE ;
Alper, H .
JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (19) :6623-6631
[3]   Poly(ε-caprolactone)-based nanocomposites:: Influence of compatibilization on properties of poly(ε-caprolactone)-silica nanocomposites [J].
Avella, M ;
Bondioli, F ;
Cannillo, V ;
Di Pace, E ;
Errico, ME ;
Ferrari, AM ;
Focher, B ;
Malinconico, M .
COMPOSITES SCIENCE AND TECHNOLOGY, 2006, 66 (7-8) :886-894
[4]   Synthesis of lipophilic dimeric C-7/C-7-linked ciprofloxacin and C-6/C-6-linked levofloxacin derivatives. Versatile in vitro biological evaluations of monomeric and dimeric fluoroquinolone derivatives as potential antitumor, antibacterial or antimycobacterial agents [J].
Azema, Joelle ;
Guidetti, Brigitte ;
Korolyov, Alexander ;
Kiss, Robert ;
Roques, Christine ;
Constant, Patricia ;
Daffe, Mamadou ;
Malet-Martino, Myriam .
EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY, 2011, 46 (12) :6025-6038
[5]   Silica-Dendrimer Core-Shell Microspheres with Encapsulated Ultrasmall Palladium Nanoparticles: Efficient and Easily Recyclable Heterogeneous Nanocatalysts [J].
Biradar, Ankush V. ;
Biradar, Archana A. ;
Asefa, Tewodros .
LANGMUIR, 2011, 27 (23) :14408-14418
[6]  
Caminade A. M., 2011, DENDRIMERS CATALYTIC
[7]   STRUCTURAL CHARACTERIZATION OF (3-AMINOPROPYL)TRIETHOXYSILANE-MODIFIED SILICAS BY SI-29 AND C-13 NUCLEAR MAGNETIC-RESONANCE [J].
CARAVAJAL, GS ;
LEYDEN, DE ;
QUINTING, GR ;
MACIEL, GE .
ANALYTICAL CHEMISTRY, 1988, 60 (17) :1776-1786
[8]  
CHERKASOV RA, 1998, RUSS CHEM REV, V67, P857, DOI [DOI 10.1070/RC1998V067N10ABEH000421, 10.1070/RC1998v067n10ABEH000421]
[9]   MAGIC-ANGLE CROSS-POLARIZATION C-13 NMR-STUDY OF AMINOSILANE COUPLING AGENTS ON SILICA SURFACES [J].
CHIANG, CH ;
LIU, NI ;
KOENIG, JL .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1982, 86 (01) :26-34
[10]   Size-selective silver nanoparticles: future of biomedical devices with enhanced bactericidal properties [J].
Dal Lago, Virginia ;
de Oliveira, Luciane Franca ;
Goncalves, Kaliandra de Almeida ;
Kobarg, Joerg ;
Cardoso, Mateus Borba .
JOURNAL OF MATERIALS CHEMISTRY, 2011, 21 (33) :12267-12273