Organic solvent-free and efficient manufacture of functionalized cellulose nanocrystals via one-pot tandem reactions

被引：59

作者：

Tang, Lirong ^{[1
]}

Huang, Biao ^{[1
]}

Yang, Nating ^{[1
]}

Li, Tao ^{[1
]}

Lu, Qilin ^{[1
]}

Lin, Wenyi ^{[1
]}

Chen, Xuerong ^{[1
]}

机构：

[1] Fujian Agr & Forestry Univ, Fuzhou, Peoples R China

来源：

GREEN CHEMISTRY | 2013年 / 15卷 / 09期

基金：

中国国家自然科学基金;

关键词：

MECHANICAL ACTIVATION; BALL; ESTERIFICATION; SURFACE; STARCH; ACIDS;

D O I：

10.1039/c3gc40965a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An environmentally benign approach for the manufacture of maleic anhydride functionalized cellulose nanocrystals (MA-CNCs) via one-pot tandem reactions with H2SO4 as a catalyst under organic solvent-free conditions was put forward. The effects of ball milling time, ultrasonication temperature and time on the yield and degree of substitution (DS) have been explored.

引用

收藏

页码：2369 / 2373

页数：5

相关论文

共 26 条

[1] Isolation and characterization of nanofibers from agricultural residues - Wheat straw and soy hulls [J].

Alemdar, Ayse ;

Sain, Mohini .

BIORESOURCE TECHNOLOGY, 2008, 99 (06) :1664-1671

[2] Organocatalytic reactions: effects of ball milling, microwave and ultrasound irradiation [J].

Bruckmann, Angelika ;

Krebs, Anke ;

Bolm, Carsten .

GREEN CHEMISTRY, 2008, 10 (11) :1131-1141

[3] Maleic anhydride incorporated onto cellulose and thermodynamics of cation-exchange process at the solid/liquid interface [J].

de Melo, Julio C. P. ;

da Silva Filho, Edson C. ;

Santana, Sirlane A. A. ;

Airoldi, Claudio .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 346 (1-3) :138-145

[4] Nanostructural Reorganization of Bacterial Cellulose by Ultrasonic Treatment [J].

Faria Tischer, Paula C. S. ;

Sierakowski, Maria Rita ;

Westfahl, Harry, Jr. ;

Tischer, Cesar Augusto .

BIOMACROMOLECULES, 2010, 11 (05) :1217-1224

[5] Controlled heterogeneous modification of cellulose fibers with fatty acids: Effect of reaction conditions on the extent of esterification and fiber properties [J].

Freire, CSR ;

Silvestre, AJD ;

Neto, CP ;

Belgacem, MN ;

Gandini, A .

JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 100 (02) :1093-1102

[6] An efficient method for determination of the degree of substitution of cellulose esters of long chain aliphatic acids [J].

Freire, CSR ;

Silvestre, AJD ;

Neto, CP ;

Rocha, RMA .

CELLULOSE, 2005, 12 (05) :449-458

[7] Effect of mechanical activation on physico-chemical properties and structure of cassava starch [J].

Huang, Zu-Qiang ;

Lu, Jian-Ping ;

Li, Xuan-Hai ;

Tong, Zhang-Fa .

CARBOHYDRATE POLYMERS, 2007, 68 (01) :128-135

[8] Influence of mechanical activation on the graft copolymerization of sugarcane bagasse and acrylic acid [J].

Huang, Zuqiang ;

Liang, Xingtang ;

Hu, Huayu ;

Gao, Li ;

Chen, Yongjun ;

Tong, Zhangfa .

POLYMER DEGRADATION AND STABILITY, 2009, 94 (10) :1737-1745

[9] Synthesis and characterization of polyvinyl alcohol/nanospherical cellulose particle films [J].

Ibrahim, Maha M. ;

El-Zawawy, Waleed K. ;

Nassar, Mona A. .

CARBOHYDRATE POLYMERS, 2010, 79 (03) :694-699

[10] Edge-carboxylated graphene nanosheets via ball milling [J].

Jeon, In-Yup ;

Shin, Yeon-Ran ;

Sohn, Gyung-Joo ;

Choi, Hyun-Jung ;

Bae, Seo-Yoon ;

Mahmood, Javeed ;

Jung, Sun-Min ;

Seo, Jeong-Min ;

Kim, Min-Jung ;

Chang, Dong Wook ;

Dai, Liming ;

Baek, Jong-Beom .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2012, 109 (15) :5588-5593