Copper(I) salt mediated 1,4-reduction of alpha,beta-unsaturated ketones using hydrosilanes

被引：44

作者：

Mori, A

Fujita, A

Nishihara, Y

Hiyama, T

机构：

[1] Res. Lab. of Resources Utilization, Tokyo Institute of Technology, Nagatsuta

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 22期

关键词：

D O I：

10.1039/a706032g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of alpha, beta-unsaturated ketones with HSiPhMe2 in the presence of CuF(PPh3)(3).2EtOH proceeds in a 1, 4-selective manner to give the corresponding saturated ketones in excellent yields.

引用

页码：2159 / 2160

页数：2

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