Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI/CuII complexes

被引：3

作者：

Zhang, XM ^{[1
]}

Tong, ML ^{[1
]}

Chen, XM ^{[1
]}

机构：

[1] Zhongshan Univ, Sch Chem & Chem Engn, State Key Lab Photoelect Mat & Technol, Guangzhou 510275, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 06期

关键词：

copper; hydroxylation; mixed-valent compounds; N ligands; reaction mechanisms;

D O I：

10.1002/1521-3773(20020315)41:6<1029::AID-ANIE1029>3.0.CO;2-B

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Structural evidence for the Gillard mechanism of covalent hydrates is provided by two mixed-valence CuI/CuII complexes containing 2,2′-bipyridine (see picture) or 1,10-phenanthroline ligands, in which a hydroxy group is added to a carbon atom adjacent to a nitrogen atom. These complexes are synthesized by hydrothermal treatment of Cu(NO3)2, the respective N,N ligand, and terephthalic acid.

引用

页码：1029 / +

页数：4

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