Hydroxylation of N-heterocycle ligands observed in two unusual mixed-valence CuI/CuII complexes

被引：3
|
作者：
Zhang, XM [1 ]
Tong, ML [1 ]
Chen, XM [1 ]
机构：
[1] Zhongshan Univ, Sch Chem & Chem Engn, State Key Lab Photoelect Mat & Technol, Guangzhou 510275, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 06期
关键词：
copper; hydroxylation; mixed-valent compounds; N ligands; reaction mechanisms;
D O I：
10.1002/1521-3773(20020315)41:6<1029::AID-ANIE1029>3.0.CO;2-B
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Structural evidence for the Gillard mechanism of covalent hydrates is provided by two mixed-valence CuI/CuII complexes containing 2,2′-bipyridine (see picture) or 1,10-phenanthroline ligands, in which a hydroxy group is added to a carbon atom adjacent to a nitrogen atom. These complexes are synthesized by hydrothermal treatment of Cu(NO3)2, the respective N,N ligand, and terephthalic acid.
引用
收藏
页码：1029 / +
页数：4
相关论文
共 50 条
  • [21] A stable 1D mixed-valence CuI/CuII coordination polymer with photocatalytic reduction activity toward Cr(VI)
    Zhong, Jun
    Yi, Xiao-Hong
    Wang, Peng
    Wang, Chong-Chen
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1183 : 256 - 262
  • [22] N-15 SOLID-STATE NMR-STUDY OF LIGANDS IN PLATINUM MIXED-VALENCE COMPLEXES
    AUSTIN, EJW
    BARRIE, PJ
    CLARK, RJH
    INORGANIC CHEMISTRY, 1992, 31 (21) : 4281 - 4285
  • [23] A mixed-valence CuII/CuI coordination polymer based on bridged thiocyanate and in situ formed di(N-heterocyclic) sulfide: Synthesis, structure, and magnetic properties
    Cui, Yanfeng
    Ding, Yuhan
    Molina, Steven Eduardo Vilcacundo
    Li, Yahong
    JOURNAL OF MOLECULAR STRUCTURE, 2021, 1241
  • [24] MIXED-VALENCE PARAMAGNETIC TRINUCLEAR COMPLEXES OF RHODIUM WITH N-ALKYLPHENOTHIAZINES
    KESHAVAN, B
    JANARDHAN, R
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1988, 27 (06): : 547 - 549
  • [25] Hydrogenation of two-electron mixed-valence iridium alkyl complexes
    Veige, AS
    Gray, TG
    Nocera, DG
    INORGANIC CHEMISTRY, 2005, 44 (01) : 17 - 26
  • [26] MIXED-VALENCE PARAMAGNETIC TRINUCLEAR RUTHENIUM COMPLEXES OF N-ALKYLPHENOTHIAZINES
    KESHAVAN, B
    JANARDHAN, R
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1987, 26 (11): : 975 - 977
  • [27] Coordinative diversity in mononuclear CuI and CuII complexes of O,N, S-ambidentate camphoriminoquinone ligands
    Filippou, Vasileios
    Bubrin, Martina
    Grupp, Anita
    Ringenberg, Mark R.
    Kaim, Wolfgang
    INORGANICA CHIMICA ACTA, 2022, 542
  • [28] Synthesis and characterization of a new hybrid-metallic complex containing mixed-valence CuI/CuII units generated by hydrothermal redox reaction
    Zhao, QH
    Wang, XF
    Liu, YQ
    Fang, RB
    CHEMISTRY LETTERS, 2004, 33 (02) : 138 - 139
  • [29] Oxovanadium (IV) complexes with tridentate N-heterocycle ligands: Synthesis, structure, and efficient catalyst for cyclohexane oxidation to cyclohexanone
    Xing, Na
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 252
  • [30] Oxidovanadium(IV) complexes with tridentate N-heterocycle ligands: Synthesis, structure, and efficient catalyst for cyclohexane oxidation to cyclohexanone
    Yan, Zhi Dan
    Xing, Na
    Zhang, Yan
    Ma, Xi Tong
    Song, Jian
    Liu, Xin
    Xing, Yong Heng
    POLYHEDRON, 2015, 102 : 600 - 608
12345