Simple Method for Manufacturing Pt Counter Electrodes on Conductive Plastic Substrates for Dye-Sensitized Solar Cells

被引：17

作者：

Gong, Yun ^{[1
]}

Li, Chunhui ^{[1
]}

Huang, Xiaoming ^{[1
]}

Luo, Yanhong ^{[1
]}

Li, Dongmei ^{[1
]}

Meng, Qingbo ^{[1
]}

Iversen, Bo Brummerstedt ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing Key Lab New Energy Mat & Devices,Key Lab, Beijing 100190, Peoples R China

来源：

ACS APPLIED MATERIALS & INTERFACES | 2013年 / 5卷 / 03期

基金：

中国国家自然科学基金;

关键词：

flexible Pt counter electrodes; dye-sensitized solar cell; press-transfer method; FILM; NANOPARTICLES; FABRICATION; WATER; SIZE;

D O I：

10.1021/am302360g

中图分类号：

TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

A novel, facile, and low-cost method was developed for manufacturing Pt counter electrodes (CEs) of dye-sensitized solar cells (DSCs) on the indium tin oxide-coated polyethylene terephthalate (ITO-PET). This press-transferring method reconciled the temperature conflict between the sintering process of thermal decomposition of H2PtCl6 and plastic substrates. Cyclic voltammograms, electrochemical impedance spectroscopy, transmittance spectra and photovoltaic performance were characterized to investigate the transferred Pt CEs. It was found that the transferred Pt CEs on ITO-PET exhibited an excellent catalytic activity comparable with traditional electrodes on FTO glasses. On the front-side, an illuminated conversion efficiency of 7.21% was reached with more than 94% efficiency of conventional thermally deposited Pt CEs on FTO glasses, and on the back-side, the illuminated conversion efficiency was 4.86%, which was higher than that for conventional electrodes.

引用

页码：795 / 800

页数：6

共 29 条

[1] Critical size of crystalline ZrO2 nanoparticles synthesized in near- and supercritical water and supercritical isopropyl alcohol [J].

Becker, Jacob ;

Hald, Peter ;

Bremholm, Martin ;

Pedersen, Jan S. ;

Chevallier, Jacques ;

Iversen, Steen B. ;

Iversen, Bo B. .

ACS NANO, 2008, 2 (05) :1058-1068

[2] A flexible carbon counter electrode for dye-sensitized solar cells [J].

Chen, Jikun ;

Li, Kexin ;

Luo, Yanhong ;

Guo, Xiaozhi ;

Li, Dongmei ;

Deng, Minghui ;

Huang, Shuqing ;

Meng, Qingbo .

CARBON, 2009, 47 (11) :2704-2708

[3] Fabrication of high performance Pt counter electrodes on conductive plastic substrate for flexible dye-sensitized solar cells [J].

Chen, Lili ;

Tan, Weiwei ;

Zhang, Jingbo ;

Zhou, Xiaowen ;

Zhang, Xiaoling ;

Lin, Yuan .

ELECTROCHIMICA ACTA, 2010, 55 (11) :3721-3726

[4] Flexible counter electrodes based on metal sheet and polymer film for dye-sensitized solar cells [J].

Fang, XM ;

Ma, TL ;

Akiyama, M ;

Guan, GQ ;

Tsunematsu, S ;

Abe, E .

THIN SOLID FILMS, 2005, 472 (1-2) :242-245

[5] Effect of the thickness of the Pt film coated on a counter electrode on the performance of a dye-sensitized solar cell [J].

Fang, XM ;

Ma, TL ;

Guan, GQ ;

Akiyama, M ;

Kida, T ;

Abe, E .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2004, 570 (02) :257-263

[6] Electrodeposition of Platinum on Plastic Substrates as Counter Electrodes for Flexible Dye-Sensitized Solar Cells [J].

Fu, NianQing ;

Xiao, XuRui ;

Zhou, XiaoWen ;

Zhang, JingBo ;

Lin, Yuan .

JOURNAL OF PHYSICAL CHEMISTRY C, 2012, 116 (04) :2850-2857

[7] Supercritical propanol-water synthesis and comprehensive size characterisation of highly crystalline anatase TiO2 nanoparticles [J].

Hald, Peter ;

Becker, Jacob ;

Bremholm, Martin ;

Pedersen, Jan S. ;

Chevallier, Jacques ;

Iversen, Steen B. ;

Iversen, Bo B. .

JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (08) :2674-2680

[8] A flexible photoelectrode for CdS/CdSe quantum dot-sensitized solar cells (QDSSCs) [J].

Huang, Xiaoming ;

Huang, Shuqing ;

Zhang, Quanxin ;

Guo, Xiaozhi ;

Li, Dongmei ;

Luo, Yanhong ;

Shen, Qing ;

Toyoda, Tara ;

Meng, Qingbo .

CHEMICAL COMMUNICATIONS, 2011, 47 (09) :2664-2666

[9] Preparation of fluorine-doped tin oxide (SnO2:F) film on polyethylene terephthalate (PET) substrate [J].

Huang, Xiaoming ;

Yu, Zhexun ;

Huang, Shuqing ;

Zhang, Quanxin ;

Li, Dongmei ;

Luo, Yanhong ;

Meng, Qingbo .

MATERIALS LETTERS, 2010, 64 (15) :1701-1703

[10] Application of carbon materials as counter electrodes of dye-sensitized solar cells [J].

Huang, Zhen ;

Liu, Xizhe ;

Li, Kexin ;

Li, Dongmei ;

Luo, Yanhong ;

Li, Hong ;

Song, Wenbo ;

Chen, LiQuan ;

Meng, Qingbo .

ELECTROCHEMISTRY COMMUNICATIONS, 2007, 9 (04) :596-598

← 1 2 3 →