High-performance polymer membranes for natural-gas sweetening

被引:188
作者
Lin, HQ
Van Wagner, E
Raharjo, R
Freeman, BD
Roman, I
机构
[1] Univ Texas, Dept Chem Engn, Ctr Energy & Environm Resources, Austin, TX 78758 USA
[2] MEDAL LP, Willow Bank Plant, Newport, DE 19804 USA
关键词
D O I
10.1002/adma.200501409
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An approach to design polymeric membranes for the removal of acid gases such as CO2 and H2S from natural gas, using a highly branched, crosslinked poly(ethylene oxide) (PEO) hydrogel, was illustrated. These solubility-selective membranes exhibited good performance for CO 2 /CH4 separation relative to the conventional size-selective membranes. Their advantages could be further enhanced by operating at low temperatures, which may provide additional flexibility for integrating membranes into natural gas processes. The results show that these polymeric membranes could be potentially used to remove polar molecules from mixtures with light gases.
引用
收藏
页码:39 / 44
页数:6
相关论文
共 29 条
[21]   Mixed-gas permeation of syngas components in poly(dimethylsiloxane) and poly(1-trimethylsilyl-1-propyne) at elevated temperatures [J].
Merkel, TC ;
Gupta, RP ;
Turk, BS ;
Freeman, BD .
JOURNAL OF MEMBRANE SCIENCE, 2001, 191 (1-2) :85-94
[22]   CYCLIC POLYETHERS AND THEIR COMPLEXES WITH METAL SALTS [J].
PEDERSEN, CJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1967, 89 (26) :7017-&
[23]  
PRASAD R, 1994, POLYM GAS SEPARATION, pCH11
[24]   THE EFFECT OF DEGREE OF ACETYLATION ON GAS SORPTION AND TRANSPORT BEHAVIOR IN CELLULOSE-ACETATE [J].
PULEO, AC ;
PAUL, DR ;
KELLEY, SS .
JOURNAL OF MEMBRANE SCIENCE, 1989, 47 (03) :301-332
[25]  
Reid R.C., 1987, PROPERTIES GASES LIQ
[26]   CORRELATION OF SEPARATION FACTOR VERSUS PERMEABILITY FOR POLYMERIC MEMBRANES [J].
ROBESON, LM .
JOURNAL OF MEMBRANE SCIENCE, 1991, 62 (02) :165-185
[27]  
Rojey A., 1997, NATURAL GAS PRODUCTI
[28]   Improvement of CO2/CH4 separation characteristics of polyimides by chemical crosslinking [J].
Staudt-Bickel, C ;
Koros, WJ .
JOURNAL OF MEMBRANE SCIENCE, 1999, 155 (01) :145-154
[29]   PROPERTIES OF A POLYIMIDE GAS SEPARATION MEMBRANE IN NATURAL-GAS STREAMS [J].
WHITE, LS ;
BLINKA, TA ;
KLOCZEWSKI, HA ;
WANG, IF .
JOURNAL OF MEMBRANE SCIENCE, 1995, 103 (1-2) :73-82