Synthesis and reactivity of nickel-hydride amino-bis-phosphinimine complexes

被引：14

作者：

Cariou, Renan ^{[1
]}

Graham, Todd W. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

DALTON TRANSACTIONS | 2013年 / 42卷 / 12期

基金：

加拿大自然科学与工程研究理事会;

关键词：

MECHANISTIC INSIGHTS; CARBON-DIOXIDE; CHEMISTRY; HYDRODESULFURIZATION; POLYMERIZATION; REDUCTION; CO2;

D O I：

10.1039/c3dt33021d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cationic hydride complexes [R-N(1,2-CH2CH2N=PPh3)(2)NiH][PF6] (R = H, Me) are prepared and shown to react with ethylene to produce NiEt complexes and with LiHBEt3 in bromobenzene to produce NiPh complexes. These species are also thermolysed at 80 degrees C to orthometallate one of the phenyl groups of the N=PPh3 substituents.

引用

页码：4237 / 4239

页数：3

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