Impact of Preparative pH on the Morphology and Photocatalytic Activity of BiVO4

被引：27

作者：

Wan, Yongbiao ^{[1
,2
]}

Wang, Sihong ^{[3
]}

Luo, Wenhao ^{[1
]}

Zhao, Lianhua ^{[1
]}

机构：

[1] Yanbian Univ, Coll Sci, Dept Chem, Yanji 133002, Jilin, Peoples R China

[2] Xinxiang Inst Occupat Dis Prevent & Control, Xinxiang 453000, Henan, Peoples R China

[3] Yanbian Univ, Anal & Test Ctr, Yanji 133002, Jilin, Peoples R China

来源：

INTERNATIONAL JOURNAL OF PHOTOENERGY | 2012年 / 2012卷

基金：

中国国家自然科学基金;

关键词：

VISIBLE-LIGHT; CRYSTAL-GROWTH; WATER; TEMPERATURE; DEGRADATION; IRRADIATION; POWDERS;

D O I：

10.1155/2012/392865

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Adjusting pH with an ammonia solution during the synthesis, single-crystalline BiVO4 has been prepared using Bi(NO3)(3)center dot 5H(2)O and NH4VO3 as starting materials through aqueous-phase precipitation at room temperature. The prepared samples are characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM). The impact of pH on structure, surface morphology, visible-light photocatalytic activity, and light absorption performance of BiVO4 is explored and discussed. During the synthesis process, neither extremely acidic (low pH) nor basic (high pH) conditions are desirable for the formation of BiVO4 in monoclinic phase. The highest photocatalytic performance on the degradation of a methylene blue solution is observed under pH = 7.0 for BiVO4 in monoclinic scheelite, which is attributed to its small grain size and marked surface oxygen evolution ability.

引用

页数：7