Quantitative analysis of a-Si1-xCx:H thin films

被引:9
作者
Gracin, D
Jaksic, M
Yang, C
Borjanovic, V
Pracek, B
机构
[1] Rudjer Boskovic Inst, Zagreb 10000, Croatia
[2] Natl Univ Singapore, Dept Phys, Singapore 119260, Singapore
[3] Fac Elect Engn & Comp, Dept Appl Phys, Zagreb 10000, Croatia
[4] Inst Surface Engn & Optoelect, Surface Anal Lab, Ljubljana 1001, Slovenia
关键词
carbon content; hydrogen content; amorphous films; backscattering; Auger spectroscopy; FTIR spectroscopy;
D O I
10.1016/S0169-4332(98)00795-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The composition of a-Si1-xCx:H films, deposited by magnetron sputtering, was measured by AES (Auger Electron Spectroscopy), RES (Rutherford Backscattering Spectrometry) using both, protons and alpha-particles, ERDA (Elastic Recoil Detection Analysis) and FTIR spectroscopy. The results obtained by all three methods show agreement in C-C/C-Si ratio within the experimental error. However, the AES somewhat underestimates the silicon concentrations, which is discussed as a consequence of chemical bonding and matrix effects. The hydrogen concentrations obtained by ERDA are typically about 30% higher than those estimated by FTIR, possibly due to the presence of non-bonded hydrogen in the film. (C) 1999 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:188 / 191
页数:4
相关论文
共 16 条
[1]   ANNEALING AND CRYSTALLIZATION PROCESSES IN A HYDROGENATED AMORPHOUS SI-C ALLOY FILM [J].
BASA, DK ;
SMITH, FW .
THIN SOLID FILMS, 1990, 192 (01) :121-133
[2]  
BRODSKY MH, 1977, PHYS REV B, V16, P3556, DOI 10.1103/PhysRevB.16.3556
[3]   PHYSICS OF AMORPHOUS-SILICON CARBON ALLOYS [J].
BULLOT, J ;
SCHMIDT, MP .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 1987, 143 (02) :345-418
[4]   VIBRATIONAL-SPECTRA OF HYDROGEN IN SILICON AND GERMANIUM [J].
CARDONA, M .
PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1983, 118 (02) :463-481
[5]   ON THE CARBON INCORPORATION INTO A-SIC-H FILMS WITH LOW-CARBON CONTENT [J].
DEOLIVEIRA, ML ;
CAMARGO, SS ;
FREIRE, FL .
JOURNAL OF APPLIED PHYSICS, 1992, 71 (03) :1531-1533
[6]  
GALE IG, 1993, PHILIPS J RES, V47, P333
[7]   MICROSTRUCTURAL PROPERTIES OF AMORPHOUS-SILICON ALLOYS DEPOSITED BY DC MAGNETRON SOURCE [J].
GRACIN, D ;
RADIC, N ;
DESNICA, UV .
VACUUM, 1995, 46 (8-10) :943-946
[8]   MICROSTRUCTURAL PROPERTIES OF DC MAGNETRON SPUTTERED A-SIH BY IR SPECTROSCOPY [J].
GRACIN, D ;
DESNICA, UV ;
IVANDA, M .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1992, 149 (03) :257-263
[9]  
LEVITT JA, 1996, NUCL INSTRUM METH B, V118, P613
[10]   OPTICAL-CONSTANTS OF AMORPHOUS HYDROGENATED CARBON AND SILICON-CARBON ALLOY-FILMS AND THEIR APPLICATION IN HIGH-TEMPERATURE SOLAR SELECTIVE SURFACES [J].
MCKENZIE, DR ;
SAVVIDES, N ;
MILLS, DR ;
MCPHEDRAN, RC ;
BOTTEN, LC .
SOLAR ENERGY MATERIALS, 1983, 9 (01) :113-126