A Zinc Complex Based on 4-Bromoisophthalic Acid and 1,2-Bi(4-pyridyl)ethane: Hydrothermal Synthesis, Crystal Structure, and Fluorescent Properties

被引：3
作者：
Han, Min-Le [1 ]
Wang, Jian-Ge [1 ]
Yao, Juan-Juan [1 ]
机构：
[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471000, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 10期
关键词：
1; 2-bi(4-pyridyl)ethane; 4-bromoisophthalic acid; crystal structure; fluorescent properties; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; LIGANDS; PHOTOLUMINESCENCE; TOPOLOGIES; CLUSTERS; DIAMINES; ZN(II);
D O I：
10.1080/15533174.2011.594838
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel zinc complex formulated as [Zn(Bript)(bpa)(H2O)](n) (1) (H(2)Bript = 4-bromoisophthalic acid, bpa = 1,2-bi(4-pyridyl) ethane) has been synthesized through hydrothermal reaction. It was structurally characterized by elemental analysis and x-ray single-crystal diffraction. The x-ray crystal structure shows that the complex belongs to monoclinic systems, P2(1)/n space group, and a = 10.997(6) angstrom, b = 14.578(8) angstrom, c = 12.963(7) angstrom, beta = 105.993(6)degrees. The adjacent Zn atoms are bridged by Bript to form a one-dimensional (1D) chain. Such 1D chains are further connected by hydrogen bonding to generate a three-dimensional (3D) supramolecular network. Fluorescence measurements show that 1 has medium fluorescent emissions at 404 nm and 468 nm upon excitation at 288 nm.
引用
收藏
页码：1268 / 1273
页数：6
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