A Zinc Complex Based on 4-Bromoisophthalic Acid and 1,2-Bi(4-pyridyl)ethane: Hydrothermal Synthesis, Crystal Structure, and Fluorescent Properties

被引：3

作者：

Han, Min-Le ^{[1
]}

Wang, Jian-Ge ^{[1
]}

Yao, Juan-Juan ^{[1
]}

机构：

[1] Luoyang Normal Univ, Coll Chem & Chem Engn, Luoyang 471000, Peoples R China

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2011年 / 41卷 / 10期

关键词：

1; 2-bi(4-pyridyl)ethane; 4-bromoisophthalic acid; crystal structure; fluorescent properties; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; LIGANDS; PHOTOLUMINESCENCE; TOPOLOGIES; CLUSTERS; DIAMINES; ZN(II);

D O I：

10.1080/15533174.2011.594838

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel zinc complex formulated as [Zn(Bript)(bpa)(H2O)](n) (1) (H(2)Bript = 4-bromoisophthalic acid, bpa = 1,2-bi(4-pyridyl) ethane) has been synthesized through hydrothermal reaction. It was structurally characterized by elemental analysis and x-ray single-crystal diffraction. The x-ray crystal structure shows that the complex belongs to monoclinic systems, P2(1)/n space group, and a = 10.997(6) angstrom, b = 14.578(8) angstrom, c = 12.963(7) angstrom, beta = 105.993(6)degrees. The adjacent Zn atoms are bridged by Bript to form a one-dimensional (1D) chain. Such 1D chains are further connected by hydrogen bonding to generate a three-dimensional (3D) supramolecular network. Fluorescence measurements show that 1 has medium fluorescent emissions at 404 nm and 468 nm upon excitation at 288 nm.

引用

页码：1268 / 1273

页数：6

共 50 条

[31] A Dicyanamido-bridged Zinc(Ⅱ) Complex Based on the Bis(4-pyridyl)ethane with a Three-dimensional Framework [J].

冯勋 ;

王利亚 ;

师新阁 ;

赵建社 ;

孙倩 .

结构化学, 2010, 29 (10) :1567-1573

[32] Hydrothermal Preparation, Crystal Structures, and Properties of New Mn(II) Metal-organic Frameworks with 4-bromoisophthalic Acid and N-donor Ligands [J].

Ma, Lu-Fang ;

Meng, Qing-Lei ;

Wang, Li-Ya ;

Liang, Fu-Pei .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2010, 40 (10) :855-860

[33] Synthesis, Crystal Structure and Properties of a Silver(I) Complex Constructed from (+)-N-Tosyl-L-glutamic Acid and 1,3-Bis(4-pyridyl)propane [J].

Zhu Xiao-Yan ;

Song Hui-Hua ;

He Rong ;

Yu Hai-Tao .

CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2012, 28 (09) :2011-2016

[34] Lanthanide coordination polymers constructed from 5-(4-pyridyl)-isophthalic acid: Synthesis, structure and photoluminescent properties [J].

Sun, Yaguang ;

Li, Jian ;

Sun, Di ;

Ding, Fu ;

Wang, Shuju ;

Xu, Zhenhe ;

Wang, Zan ;

Smet, Philippe F. ;

Meert, Katrien W. ;

Poelman, Dirk .

INORGANIC CHEMISTRY COMMUNICATIONS, 2013, 35 :221-225

[35] A new Co(II) coordination polymer with the 2-(4-pyridyl)-terephthalate ligand: synthesis, crystal structure and magnetic properties [J].

Tian, Danian ;

Ding, Runmei ;

Chen, Bingbing ;

Cen, Peipei .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2019, 74 (7-8) :619-622

[36] Two New Cu(II) Coordination Polymers Based on 1,2-bi(4-pyridyl)ethene and 4-R-phthalic acid (R = -C(CH3)3 or -CH3): Syntheses, Structures, and Characteristics [J].

Han, Min-Le ;

Liu, Jing ;

Wang, Sheng-Chun ;

Liu, Guang-Zhen ;

Du, De-Guang .

SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2016, 46 (03) :338-342

[37] Crystal structure of catena-poly[triaqua(μ2-1,2-bis(4-pyridyl)ethane-κ2N:N′)-(1,2-bis(4-pyridyl)ethane-κN)nickel(II)] 2-aminonicotinate nitrate-1,2-bis(4-pyridyl)ethane - water (2/1/8), C36H44N8NiO12 [J].

Wang, Yu-Fang ;

Wei, Jing-jing ;

Zhai, Xiao-Hui .

ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2018, 233 (03) :383-385

[38] One-Dimensional Copper(II) Coordination Polymer Based on 1,2-bis-(4-Pyridyl) Ethane and 1,10-Phenathroline [J].

Kawade, Vitthal A. ;

Bhat, Satish S. ;

Naveen, S. ;

Lokanath, N. K. ;

Butcher, R. J. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2023, 64 (07) :1341-1349

[39] Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties [J].

Zaguzin, Alexander S. ;

Sukhikh, Taisiya S. ;

Sakhapov, Ilyas F. ;

Fedin, Vladimir P. ;

Sokolov, Maxim N. ;

Adonin, Sergey A. .

MOLECULES, 2022, 27 (04)

[40] Synthesis and crystal structure of one-dimensional zinc(II) polymer constructed by salicylate and trans-1,2-bis(4-pyridyl)ethylene [J].

Jung, Eun Ju ;

Lee, Uk ;

Koo, Bon Kweon .

INORGANICA CHIMICA ACTA, 2009, 362 (05) :1655-1659

← 1 2 3 4 5 →