Synthesis and properties of glycolaldehyde di- and triphosphate

被引：0
|
作者：
Lawrence, AJ [1 ]
Sutherland, JD [1 ]
机构：
[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England
来源：
SYNLETT | 2002年 / 01期
关键词：
aldehydes; bioorganic chemistry; ozonolysis; phosphorylations; photochemistry;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Use of photolabile acetal protecting groups enables the synthesis of glycolaldehyde di- and triphosphate 4 and 5, which undergo enolisation at significantly lower pH values than glycolaldehyde phosphate 1. At pH > 10, 5 is converted to 1 and inorganic pyrophosphate.
引用
收藏
页码：170 / 172
页数：3
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