Synthesis and properties of glycolaldehyde di- and triphosphate

被引：0

作者：

Lawrence, AJ ^{[1
]}

Sutherland, JD ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

SYNLETT | 2002年 / 01期

关键词：

aldehydes; bioorganic chemistry; ozonolysis; phosphorylations; photochemistry;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Use of photolabile acetal protecting groups enables the synthesis of glycolaldehyde di- and triphosphate 4 and 5, which undergo enolisation at significantly lower pH values than glycolaldehyde phosphate 1. At pH > 10, 5 is converted to 1 and inorganic pyrophosphate.

引用

页码：170 / 172

页数：3

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