Reactive intermediates from carbonylation of ruthenium(I) carbonyl carboxylates. Isolation, molecular structures and chemical properties of dinuclear unbridged ruthenium carbonyl trifluoroacetates

被引：8

作者：

Funaioli, T

Marchetti, F

Fachinetti, G

机构：

[1] Univ Pisa, Dipartimento Chim & Chim Ind, I-56126 Pisa, Italy

[2] Univ Rome La Sapienza, Dipartimento Ingn Chim Mat Mat Prime & Met, I-00195 Rome, Italy

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 20期

关键词：

D O I：

10.1039/a905798f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carboxylato-bridged Ru(I) carbonyl complexes are activated by CO towards both disproportionation and reaction with dihydrogen, through the intermediacy of the unbridged metal-metal bonded valence isomers (OC)(5)RuRu(CO)(3)- (OCOCR3)(2) and [Ru(CO)(4)(OCOCR3)](2).

引用

页码：2043 / 2044

页数：2

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