Propylene sulfite as film-forming electrolyte additive in lithium ion batteries

被引：121
|
作者：
Wrodnigg, GH
Wrodnigg, TM
Besenhard, JO
Winter, M
机构：
[1] Graz Univ Technol, Inst Chem Technol Inorgan Mat, A-8010 Graz, Austria
[2] Graz Univ Technol, Inst Organ Chem, A-8010 Graz, Austria
来源：
ELECTROCHEMISTRY COMMUNICATIONS | 1999年 / 1卷 / 3-4期
基金：
奥地利科学基金会;
关键词：
lithium ion batteries; graphite anodes; LiMn4O4; cathodes; electrolyte additives; propylene sulfite;
D O I：
10.1016/S1388-2481(99)00023-5
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Propylene sulfite (PS) has been studied as a film-forming electrolyte additive for use in lithium ion battery electrolytes. Even small amounts in the order of 5 vol.% PS suppress propylene carbonate (PC) co-intercalation into graphite. In addition, a 1 M LiClO4/PC/PS (95:5 by volume) electrolyte is characterised by a high oxidation stability at a LiMn2O4 cathode. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：148 / 150
页数：3
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