Nanostructured organic electrolytes

被引:49
作者
Cho, Byoung-Ki [1 ,2 ]
机构
[1] Dankook Univ, Dept Chem, Gyeonggi Do 448701, South Korea
[2] Dankook Univ, Inst Nanosensor & Biotechnol, Gyeonggi Do 448701, South Korea
来源
RSC ADVANCES | 2014年 / 4卷 / 01期
关键词
LIQUID-CRYSTALLINE ASSEMBLIES; BLOCK-COPOLYMER ELECTROLYTES; BICONTINUOUS CUBIC PHASES; POLYMER ELECTROLYTES; IONIC-CONDUCTIVITY; SELF-ORGANIZATION; MOLECULAR-WEIGHT; LITHIUM SALT; OXYETHYLENE MOIETIES; POLY(BENZYL ETHER);
D O I
10.1039/c3ra45044a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This review introduces research work in the area of organic liquid crystalline (LC) electrolytes consisting of ionophilic and ionophobic groups. I discuss the LC phase behavior and morphology-dependent ion conduction of organic electrolyte systems based upon (i) coil-coil block copolymers (BCP), (ii) dendritic BCPs, (iii) mini-dendron-based liquid crystals, and (iv) rod-type liquid crystals. As a way to improve ionic conductivity and mechanical strength, the self-assembling approach of each LC system and other processes including macroscopic alignment techniques and post-polymerizations are described.
引用
收藏
页码:395 / 405
页数:11
相关论文
共 74 条
  • [21] Co-organisation of ionic liquids with amphiphilic diethanolamines: construction of 3D continuous ionic nanochannels through the induction of liquid-crystalline bicontinuous cubic phases
    Ichikawa, Takahiro
    Yoshio, Masafumi
    Taguchi, Satomi
    Kagimoto, Junko
    Ohno, Hiroyuki
    Kato, Takashi
    [J]. CHEMICAL SCIENCE, 2012, 3 (06) : 2001 - 2008
  • [22] Induction of Thermotropic Bicontinuous Cubic Phases in Liquid-Crystalline Ammonium and Phosphonium Salts
    Ichikawa, Takahiro
    Yoshio, Masafumi
    Hamasaki, Atsushi
    Taguchi, Satomi
    Liu, Feng
    Zeng, Xiang-bing
    Ungar, Goran
    Ohno, Hiroyuki
    Kato, Takashi
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (05) : 2634 - 2643
  • [23] 3D Interconnected Ionic Nano-Channels Formed in Polymer Films: Self-Organization and Polymerization of Thermotropic Bicontinuous Cubic Liquid Crystals
    Ichikawa, Takahiro
    Yoshio, Masafumi
    Hamasaki, Atsushi
    Kagimoto, Junko
    Ohno, Hiroyuki
    Kato, Takashi
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (07) : 2163 - 2169
  • [24] Uniaxially parallel alignment of a smectic a liquid-crystalline rod-coil molecule and its lithium salt complexes using rubbed polyimides
    Iinuma, Yosuke
    Kishimoto, Kenji
    Sagara, Yoshimitsu
    Yoshio, Masafumi
    Mukai, Tomohiro
    Kobayashi, Ichiro
    Ohno, Hiroyuki
    Kato, Takashi
    [J]. MACROMOLECULES, 2007, 40 (14) : 4874 - 4878
  • [25] Lithium ion induced nanophase ordering and ion mobility in ionic block copolymers
    Ioannou, Eirini F.
    Mountrichas, Grigoris
    Pispas, Stergios
    Kamitsos, Efstratios I.
    Floudas, George
    [J]. MACROMOLECULES, 2008, 41 (16) : 6183 - 6190
  • [26] CHARGE DISCHARGE CHARACTERISTICS OF CARBON-FIBER WITH GRAPHITE STRUCTURE IN ORGANIC ELECTROLYTES CONTAINING LITHIUM TRIFLUOROMETHANESULFATE AND LITHIUM HEXAFLUOROPHOSPHATE
    ISHIKAWA, M
    MORITA, M
    ASAO, M
    MATSUDA, Y
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (05) : 1105 - 1108
  • [27] Functional liquid-crystalline assemblies: Self-organized soft materials
    Kato, T
    Mizoshita, N
    Kishimoto, K
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (01) : 38 - 68
  • [28] New Type of Li Ion Conductor with 3D Interconnected Nanopores via Polymerization of a Liquid Organic Electrolyte-Filled Lyotropic Liquid-Crystal Assembly
    Kerr, Robert L.
    Miller, Seth A.
    Shoemaker, Richard K.
    Elliott, Brian J.
    Gin, Douglas L.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (44) : 15972 - +
  • [29] Hydrophilic Matrix-Assisted Ionic Transportation in the Columnar Assembly of Amphiphilic Dendron-Coils
    Kim, Hyun-Yu
    Song, Jie
    Kim, Seung-Hyun
    Lee, Eunji
    Lee, Jeong-Kyu
    Zin, Wang-Cheol
    Cho, Byoung-Ki
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (35) : 8683 - 8686
  • [30] Nano-segregated polymeric film exhibiting high ionic conductivities
    Kishimoto, K
    Suzawa, T
    Yokota, T
    Mukai, T
    Ohno, H
    Kato, T
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (44) : 15618 - 15623