Mass spectra of new heterocycles: XIV. Investigation of 2-(alkyl- and propargylsulfanyl)-3-(ferrocenylmethoxy)pyrroles by electron ionization and laser desorption/ionization

被引：4

作者：

Klyba, L. V. ^{[1
]}

Tarasova, O. A. ^{[1
]}

Nedolya, N. A. ^{[1
]}

Sanzheeva, E. R. ^{[1
]}

机构：

[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, Ul Favorskogo 1, Irkutsk 664033, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2016年 / 52卷 / 11期

关键词：

FERROCENE; SPECTROMETRY; PYRROLES; 2,5-DIMETHYL-1-PHENYLPYRROLE; FRAGMENTATION;

D O I：

10.1134/S1070428016110063

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By mass spectrometry methods applying electron ionization (70 eV) and laser desorption/ionization (NALDI, MALDI) 1-(alkyl-, cycloalkyl-, vinyloxyethyl-, and aryl)substituted 2-(alkyl- and propargylsulfanyl)-3-(ferrocenylmethoxy)pyrroles were studied and characterized. At the electron ionization the peak of the molecular ion possesses very low intensity. The main fraction ions are the ferrocenylmethyl ion (the most abundant peak) and its decomposition ions. Under the NALDI conditions molecular ions and protonated molecules [M + H](+) are generated. The general fragmentation rules in the field-free region are determined. By an example of 1-phenyl derivative of pyrrole the MALDI procedure was also demonstrated to be suitable for investigation of 2-(alkylsulfanyl)-3-(ferrocenylmethoxy)pyrroles.

引用

页码：1587 / 1592

页数：6