Sulfonic Acid Resin-Catalyzed Oxidation of Aldehydes to Carboxylic Acids by Hydrogen Peroxide

被引：11

作者：

Yang, Xiaomei ^{[1
]}

Tang, Si ^{[1
]}

Lu, Tianliang ^{[1
]}

Chen, Chen ^{[2
]}

Zhou, Lipeng ^{[1
]}

Su, Yunlai ^{[1
]}

Xu, Jie ^{[2
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Peoples R China

[2] Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2013年 / 43卷 / 07期

关键词：

Aldehydes; carboxylic acids; hydrogen peroxide; oxidation; sulfonic acid resin; AROMATIC-ALDEHYDES; SELECTIVE OXIDATION; ORGANIC-SOLVENT;

D O I：

10.1080/00397911.2011.617487

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Oxidation of benzaldehyde to benzoic acid can be performed efficiently with 30% H2O2 as the oxidant and sulfonic acid resin Amberlyst 15 as the catalyst. The reactivities of benzaldehyde derivatives are determined by both hindrance effect and electron effect of substituents, and benzaldehyde derivatives with electron-withdrawing group at the meta- or para-position are highly active and almost quantitatively converted into their corresponding acids. In addition, this method also works well for the oxidation of aliphatic aldehydes. The key characteristic of the procedure is that the catalyst is recyclable.

引用

页码：979 / 985

页数：7

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