Synthesis and Crystal Structure of Three New Zn(II), Ni(II) and Mn(II) Coordination Polymers Based on Asymmetric Dicarboxylate Ligand

被引：3

作者：

Yang, Lili ^{[1
]}

机构：

[1] Weihai Vocat Coll, Dept Biol Chem Engn, Weihai 264210, Shandong, Peoples R China

来源：

JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS | 2012年 / 22卷 / 04期

关键词：

Coordination polymer; Crystal structure; Asymmetric dicarboxylate; DIPHENIC ACID; HYDROTHERMAL SYNTHESIS; CADMIUM(II) COMPLEXES; METAL-COMPLEXES;

D O I：

10.1007/s10904-011-9626-z

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Three new coordination polymers [Zn(pda)(H2O)](n) (1), [Ni(pda)(bib)(1.5)](n) (2) and [Mn-2(pda)(2)(bimb)](n) (3) [H(2)pda = 3,4'-biphenyl-dicarboxylic acid, bib = 4,4'-bis (2-imidazol-1-ylmethyl) biphenyl and bmib = 4,4'-bis (2-methylimidazol-1-ylmethyl)biphenyl] have been synthesized and structurally characterized by elemental analysis, IR and X-ray diffraction. Single-crystal X-ray analyses revealed that that pda ligand acts as bridging ligand, exhibiting rich coordination modes to link metal ions: monodentate, bidentate chelating, bis-monodentate and chelating/bridging fashions. Compound 1 and 2 demonstrate a one-dimensional chain. Compound 3 is a two-dimensional (4,4) layer structure. Furthermore, the solid state luminescence spectrum of compound 1 is investigated at room temperature.

引用

页码：709 / 716

页数：8

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