Exact theory of dense amorphous hard spheres in high dimension I. The free energy

被引:76
作者
Kurchan, Jorge [1 ]
Parisi, Giorgio [2 ]
Zamponi, Francesco [3 ]
机构
[1] PMMH Ecole Super Phys & Chim Ind, F-75231 Paris 05, France
[2] Univ Roma La Sapienza, Dipartimento Fis, Ist Nazl Fis Nucl, IPFC CNR,Sez Roma 1, I-00185 Rome, Italy
[3] Ecole Normale Super, LPT, CNRS, UMR 8549, F-75005 Paris, France
关键词
cavity and replica method; disordered systems (theory); structural glasses (theory); MEAN-FIELD THEORY; GLASS-TRANSITION;
D O I
10.1088/1742-5468/2012/10/P10012
中图分类号
O3 [力学];
学科分类号
08 ; 0801 ;
摘要
We consider the theory of the glass transition and jamming of hard spheres in the large space dimension limit. Previous investigations were based on the assumption that the probability distribution within a 'cage' is Gaussian, which is not fully consistent with numerical results. Here we perform a replica calculation without making any assumption on the cage shape. We show that thermodynamic functions turn out to be exact within the Gaussian ansatz-provided one allows for arbitrary replica symmetry breaking-and indeed agree well with numerical results. The actual structure function (the so-called non-ergodic parameter) is not Gaussian, an apparent paradox which we discuss. In this paper we focus on the free energy, future papers will present the results for the structure functions and a detailed comparison with numerical results.
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页数:20
相关论文
共 18 条
[1]  
[Anonymous], 2011, DYNAMICAL HETEROGENE
[2]  
[Anonymous], 2012, STRUCTURAL GLASSES S
[3]   Dimensional study of the caging order parameter at the glass transition [J].
Charbonneau, Patrick ;
Ikeda, Atsushi ;
Parisi, Giorgio ;
Zamponi, Francesco .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2012, 109 (35) :13939-13943
[4]  
Conway J.H., 1993, SPHERE PACKINGS LATT
[5]   CLASSICAL HARD-SPHERE FLUID IN INFINITELY MANY DIMENSIONS [J].
FRISCH, HL ;
RIVIER, N ;
WYLER, D .
PHYSICAL REVIEW LETTERS, 1985, 54 (19) :2061-2063
[6]   High dimensionality as an organizing device for classical fluids [J].
Frisch, HL ;
Percus, JK .
PHYSICAL REVIEW E, 1999, 60 (03) :2942-2948
[7]   RANDOM SOLUTIONS FROM A REGULAR DENSITY FUNCTIONAL HAMILTONIAN - A STATIC AND DYNAMICAL THEORY FOR THE STRUCTURAL GLASS-TRANSITION [J].
KIRKPATRICK, TR ;
THIRUMALAI, D .
JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1989, 22 (05) :L149-L155
[8]   CONNECTIONS BETWEEN SOME KINETIC AND EQUILIBRIUM THEORIES OF THE GLASS-TRANSITION [J].
KIRKPATRICK, TR ;
WOLYNES, PG .
PHYSICAL REVIEW A, 1987, 35 (07) :3072-3080
[9]   Large Deviations of the Maximum Eigenvalue for Wishart and Gaussian Random Matrices [J].
Majumdar, Satya N. ;
Vergassola, Massimo .
PHYSICAL REVIEW LETTERS, 2009, 102 (06)
[10]   Dynamical transition of glasses: From exact to approximate [J].
Mari, Romain ;
Kurchan, Jorge .
JOURNAL OF CHEMICAL PHYSICS, 2011, 135 (12)