Synthesis and structure of a layered zinc phosphate-acetate, [C5H10NH2]2[Zn(ZnO2CCH3)(PO4)(HPO4)]

被引：9
|
作者：
Natarajan, S [1 ]
机构：
[1] Jawaharlal Nehru Ctr Adv Sci Res, Framework Solids Lab, Chem & Phys Mat Unit, Bangalore 56064, Karnataka, India
来源：
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 09期
关键词：
D O I：
10.1039/b200642c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The solution-mediated synthesis and single crystal structure of an inorganic-organic hybrid solid [C5H10NH2](2)-[ Zn(ZnO2CCH3)(PO4)(HPO4)], I, is presented. The structure of I is built up from a network of ZnO4, ZnO3(OAc) and PO3(OH) tetrahedral units, connected through their vertices, forming macroanionic two-dimensional sheets with four- and eight-membered apertures. The acetate groups are perpendicular to the plane of the layers and project from the Zn center into the inter-lamellar region. The charge compensating organic cations, piperidinium, are also located in between the layers. The connectivity within the layers shows close similarity to the three-dimensional zinc phosphate with gismondine topology.
引用
收藏
页码：2088 / 2091
页数：4
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