Hetero Diels-Alder reaction of olefin with o-quinone methides generated using (±)-binolphosphoric acid for the stereoselective synthesis of 2,4-diarylbenzopyrans: application to the formal synthesis of myristinin B/C

被引：45

作者：

Gharpure, Santosh J. ^{[1
,2
]}

Sathiyanarayanan, A. M. ^{[1
]}

Vuram, Prasanna K. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India

[2] Indian Inst Technol, Dept Chem, Bombay 400076, Maharashtra, India

来源：

RSC ADVANCES | 2013年 / 3卷 / 40期

关键词：

VINYLOGOUS CARBONATES; HYDROXYBENZYL ALCOHOLS; BIOMIMETIC SYNTHESIS; IN-SITU; CYCLIZATION; ALKYLATION; QUINONEMETHIDES; CONSTRUCTION; INHIBITORS; PHENOLS;

D O I：

10.1039/c3ra43526a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Hetero Diels-Alder reaction of olefin with o-quinone methides (o-QMs) generated using (+/-)-binolphosphoric acid was developed for the stereoselective synthesis of 2,4-diarylbenzopyrans. The method thus developed was utilized in the formal synthesis of myristinin B/C.

引用

页码：18279 / 18282

页数：4

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