Synthesis, characterization and optical properties of fluorinated poly(aryl ether)s containing phthalazinone moieties

被引：28
作者：
Song, Yuan
Wang, Jinyan
Li, Guanghui
Sun, Qingmin
Jian, Xigao [1 ,3 ]
Teng, Jie [2 ,3 ]
Zhang, Hongbo
机构：
[1] Dalian Univ Technol, Dept Polymer Sci & Mat, State Key Lab Fine Chem, Dalian 116012, Liaoning, Peoples R China
[2] Dalian Univ Technol, Sch Phys & Optoelect Technol, Dalian 116023, Peoples R China
[3] Dalian Univ Technol, Photon Res Ctr, Dalian 116023, Peoples R China
来源：
POLYMER | 2008年 / 49卷 / 23期
基金：
中国国家自然科学基金;
关键词：
Polymer optical waveguide; Fluorinated poly(aryl ether); Phthalazinone;
D O I：
10.1016/j.polymer.2008.09.003
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A series of novel fluorinated poly(aryl ether)s containing phthalazinone moieties (FPPEs) have been prepared by a modified synthetic procedure for optical waveguide applications. The obtained random copolymers exhibited excellent solubility in polar organic solvents, high glass transition temperatures (T(g)s: 185-269 degrees C), good thermal stabilities (the temperatures of 1% weight loss: 487-510 degrees C) and good optical properties. By adjusting the feed ratio of the reactants, the refractive indices of TE and TM modes (at 1550 nm) could be well controlled in the range of 1.575-1.498 and 1.552-1.484, respectively. The optical losses of the FPPEs exhibited relatively low values (less than 0.27 dB/cm at 1310 nm). Additionally, the thermo-optic coefficient (dn/dT) values of the FPPEs at 1310 nm and 1550 nm (TE mode) ranged from -0.97 x 10(-4) C to -1.33 x 10(-4) degrees C and from -0.96 x 10(-4) degrees C to -1.29 x 10(-4) degrees C, respectively. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：4995 / 5001
页数：7
相关论文
共 42 条
[1]   Controlled refractive index polymers: Polyphosphazenes with chlorinated- and fluorinated-, aryloxy- and alkoxy- side-groups [J].
Allcock, HR ;
Bender, JD ;
Chang, YK ;
McKenzie, M ;
Fone, MM .
CHEMISTRY OF MATERIALS, 2003, 15 (02) :473-477
[2]   Synthesis and polymerization of trifluorovinylether-terminated imide oligomers. I [J].
Choi, WS ;
Harris, FW .
POLYMER, 2000, 41 (16) :6213-6221
[3]   A low temperature polycondensation for the preparation of highly fluorinated poly(arylene ether sulfone)s containing crosslinkable pentafluorostyrene moieties [J].
Ding, JF ;
Qi, YH ;
Day, M ;
Jiang, J ;
Callender, CL .
MACROMOLECULAR CHEMISTRY AND PHYSICS, 2005, 206 (23) :2396-2407
[4]   Highly fluorinated poly(arylene alkylene ether sulfone)s: Synthesis and thermal properties [J].
Ding, Jianfu ;
Du, Xiaomei ;
Day, Michael ;
Jiang, Jia ;
Callender, Claire L. ;
Stupak, Jacek .
MACROMOLECULES, 2007, 40 (09) :3145-3153
[5]   Advances in polymer integrated optics [J].
Eldada, L ;
Shacklette, LW .
IEEE JOURNAL OF SELECTED TOPICS IN QUANTUM ELECTRONICS, 2000, 6 (01) :54-68
[6]   Optical properties of perfluorocyclobutane aryl ether polymers for polymer photonic devices [J].
Ghim, J ;
Lee, DS ;
Shin, BG ;
Vak, D ;
Yi, DK ;
Kim, MJ ;
Shim, HS ;
Kim, JJ ;
Kim, DY .
MACROMOLECULES, 2004, 37 (15) :5724-5731
[7]  
Han K, 2000, J APPL POLYM SCI, V77, P2172, DOI 10.1002/1097-4628(20000906)77:10<2172::AID-APP10>3.0.CO
[8]  
2-9
[9]   Optimizing fluorinated poly(arylene ether)s for optical waveguide applications [J].
Jiang, J ;
Callender, CL ;
Blanchetiere, C ;
Jacob, S ;
Noad, JP ;
Ding, JF ;
Qi, YH ;
Day, M .
OPTICAL MATERIALS, 2006, 28 (03) :189-194
[10]   Arrayed waveguide gratings based on perfluorocyclobutane polymers for CWDM applications [J].
Jiang, J ;
Callender, CL ;
Blanchetière, C ;
Noad, JP ;
Chen, SR ;
Ballato, J ;
Smith, DW .
IEEE PHOTONICS TECHNOLOGY LETTERS, 2006, 18 (1-4) :370-372
12345