Novel morphology-controlled synthesis of homogeneous LiFePO4 for Li-ion batteries using an organic phosphate source

被引:13
作者
Park, Youngjin [1 ,2 ]
Roh, Kwang Chul [3 ]
Shin, Woonsup [1 ,2 ]
Lee, Jae-Won [4 ]
机构
[1] Sogang Univ, Interdisciplinary Program Integrated Biotechnol, Dept Chem, Seoul 121742, South Korea
[2] Sogang Univ, Inorgan & Biomat Ctr BK 21, Seoul 121742, South Korea
[3] Korea Inst Ceram Engn & Technol, Seoul 153801, South Korea
[4] Dankook Univ, Dept Energy Engn, Cheonan 330714, South Korea
来源
RSC ADVANCES | 2013年 / 3卷 / 34期
基金
新加坡国家研究基金会;
关键词
CATHODE MATERIAL; ELECTROCHEMICAL PROPERTIES; SOLVOTHERMAL SYNTHESIS; HYDROTHERMAL SYNTHESIS; LITHIUM; PERFORMANCE; IRON; PRECIPITATION; NANOPARTICLES; OLIVINES;
D O I
10.1039/c3ra42035c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Homogeneous LiFePO4 nanoplates or hollow spheres can be selectively synthesized with a phosphate ester just by changing the mixing sequence in a hydrothermal synthetic process. When the iron source was mixed first, nanoplates were formed, and mixing the lithium source first resulted in hollow spheres. Both structures performed well as cathode materials in Li-ion batteries.
引用
收藏
页码:14263 / 14266
页数:4
相关论文
共 38 条
  • [1] Fine-particle lithium iron phosphate LiFePO4 synthesized by a new low-cost aqueous precipitation technique
    Arnold, G
    Garche, J
    Hemmer, R
    Ströbele, S
    Vogler, C
    Wohlfahrt-Mehrens, A
    [J]. JOURNAL OF POWER SOURCES, 2003, 119 : 247 - 251
  • [2] Lithium iron(II) phospho-olivines prepared by a novel carbothermal reduction method
    Barker, J
    Saidi, MY
    Swoyer, JL
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2003, 6 (03) : A53 - A55
  • [3] A versatile method of preparation of carbon-rich LiFePO4:: A promising cathode material for Li-ion batteries
    Bauer, EM
    Bellitto, C
    Righini, G
    Pasquali, M
    Dell'Era, A
    Prosini, PP
    [J]. JOURNAL OF POWER SOURCES, 2005, 146 (1-2) : 544 - 549
  • [4] Electronically conductive phospho-olivines as lithium storage electrodes
    Chung, SY
    Bloking, JT
    Chiang, YM
    [J]. NATURE MATERIALS, 2002, 1 (02) : 123 - 128
  • [5] Size effects on carbon-free LiFePO4 powders
    Delacourt, C.
    Poizot, P.
    Levasseur, S.
    Masquelier, C.
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (07) : A352 - A355
  • [6] Lithium deintercalation in LiFePO4 nanoparticles via a domino-cascade model
    Delmas, C.
    Maccario, M.
    Croguennec, L.
    Le Cras, F.
    Weill, F.
    [J]. NATURE MATERIALS, 2008, 7 (08) : 665 - 671
  • [7] Identification of surface impurities on LiFePO4 particles prepared by a hydrothermal process
    Dokko, K
    Shiraishi, K
    Kanamura, K
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2005, 152 (11) : A2199 - A2202
  • [8] Electrochemical properties of LiFePO4 prepared via hydrothermal route
    Dokko, Kaoru
    Koizumi, Shohei
    Sharaishi, Keisuke
    Kanamura, Kiyoshi
    [J]. JOURNAL OF POWER SOURCES, 2007, 165 (02) : 656 - 659
  • [9] Particle morphology, crystal orientation, and electrochemical reactivity of LiFePO4 synthesized by the hydrothermal method at 443 K
    Dokko, Kaoru
    Koizumi, Shohei
    Nakano, Hiroyuki
    Kanamura, Kiyoshi
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (45) : 4803 - 4810
  • [10] Porous olivine composites synthesized by sol-gel technique
    Dominko, R
    Bele, M
    Gaberscek, M
    Remskar, M
    Hanzel, D
    Goupil, JM
    Pejovnik, S
    Jamnik, J
    [J]. JOURNAL OF POWER SOURCES, 2006, 153 (02) : 274 - 280