Electron-transfer reactions across liquid/liquid interfaces

被引：47
作者：
Schmickler, W [1 ]
机构：
[1] UNIV ULM, ABT ELEKTROCHEM, D-89069 ULM, GERMANY
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1997年 / 428卷 / 1-2期
关键词：
electron transfer; potential dependence; liquid/liquid interfaces; numerical modelling;
D O I：
10.1016/S0022-0728(96)05076-0
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
We present a general expression for the rate of an electron-transfer reaction across liquid/liquid interfaces. Since the variation of the inner potential in the boundary region is small, a change in the potential drop across the interface has little effect on the free energy of the reaction, but affects mainly the concentrations of the reactants. This argument is supported by explicit model calculations. (C) 1997 Elsevier Science S.A.
引用
收藏
页码：123 / 127
页数：5
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