Syntheses, structures, and properties of CdII and CoII complexes with 5-(pyridin-4-yl)isophthalate

被引：13

作者：

Hou, Chao ^{[1
]}

Zhao, Yue ^{[1
]}

Okamura, Taka-Aki ^{[2
]}

Wang, Peng ^{[1
]}

Sun, Wei-Yin ^{[1
]}

机构：

[1] Nanjing Univ, Coordinat Chem Inst, State Key Lab Coordinat Chem, Sch Chem & Chem Engn,Nanjing Natl Lab Microstruct, Nanjing 210093, Jiangsu, Peoples R China

[2] Osaka Univ, Dept Macromol Sci, Grad Sch Sci, Toyonaka, Osaka 5600043, Japan

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 24期

基金：

中国国家自然科学基金;

关键词：

CdII complex; CoII complex; Crystal structure; Photoluminescence; METAL-ORGANIC FRAMEWORKS; SECONDARY BUILDING UNITS; COORDINATION POLYMERS; LUMINESCENT PROPERTIES; SORPTION PROPERTIES; CRYSTAL-STRUCTURE; LIGAND SYNTHESIS; ACID; TEMPERATURE; TOPOLOGY;

D O I：

10.1080/00958972.2012.742890

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A N-donor containing carboxylic ligand, 5-(pyridin-4-yl)isophthalic acid (H2L), was applied to construct two new coordination polymers [Cd(L)(DMF)] n (1, DMF?=?N,N-dimethylformamide) and {[Co(L)(H2O)2]?.?0.5CH3OH?.?1.5H2O} n (2) under different conditions. The complexes were characterized by IR, elemental, and thermogravimetric analyses, powder and single crystal X-ray diffraction. In 1 each L2- links four CdII to form a 3-D framework, while in 2 each L2- connects three metals to form a 2-D layer structure, which is further connected together by hydrogen bonds to form a 3-D architecture. The thermal stability of the complexes and the photoluminescence of 1 were investigated.

引用

页码：4409 / 4418

页数：10

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