Small but Strong Lessons from Chemistry for Nanoscience

被引:65
作者
Hoffmann, Roald [1 ]
机构
[1] Cornell Univ, Dept Chem & Chem Biol, Baker Lab, Ithaca, NY 14853 USA
基金
美国国家科学基金会;
关键词
clusters; nanoscience; nanosheets; surfaces; TERNARY GOLD POLYPHOSPHIDES; WALLED CARBON NANOTUBES; OXIDATION-STATE ZERO; CDSE NANOCRYSTALS; ELECTRONIC-PROPERTIES; METAL-CLUSTERS; MAIN-GROUP; PLASMONIC NANOSTRUCTURES; COLLOIDAL NANOCRYSTALS; SEMICONDUCTOR CLUSTERS;
D O I
10.1002/anie.201206678
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In a different light: In a provocative look at nanoscience, Nobel Laureate Roald Hoffmann considers the structural and electronic perplexities of dimensionality, the consequences of bond severance in nanoobject formation, the implications of simple acid-base chemistry for stabilization of nanostructures, and what lessons might be learned from surface science on structural relaxation and reconstruction. © 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:93 / 103
页数:11
相关论文
共 112 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   Ziegler-type hydrogenation catalysts made from group 8-10 transition metal precatalysts and AIR3 cocatalysts: A critical review of the literature [J].
Alley, William M. ;
Hamdemir, Isil K. ;
Johnson, Kimberly A. ;
Finke, Richard G. .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 315 (01) :1-27
[3]   Matrix infrared spectra and density functional calculations of transition metal hydrides and dihydrogen complexes [J].
Andrews, L .
CHEMICAL SOCIETY REVIEWS, 2004, 33 (02) :123-132
[4]  
[Anonymous], ANGEW CHEM
[5]  
[Anonymous], John
[6]  
[Anonymous], SOLIDS AND SURFACES
[7]  
Bader R. F. W., 1994, ATOMS MOL QUANTUM TH
[8]   Phase transitions in various kinds of clusters [J].
Berry, R. S. ;
Smirnov, B. M. .
PHYSICS-USPEKHI, 2009, 52 (02) :137-164
[9]  
Bhushan B, 2004, SPRINGER HANDBOOK OF NANOTECHNOLOGY, P99, DOI 10.1007/3-540-29838-X_4
[10]   Table salt and other alkali metal chloride oligomers:: Structure, stability, and bonding [J].
Bickelhaupt, F. Matthias ;
Sola, Miquel ;
Guerra, Céllia Fonseca .
INORGANIC CHEMISTRY, 2007, 46 (13) :5411-5418