Self-assembly into temperature dependent micro-/nano-aggregates of 5,10,15,20-tetrakis(4-carboxyl phenyl)-porphyrin

被引：23
作者：
Liu, Qingyun [1 ]
Zhou, Hangyue [1 ]
Zhu, Jiqin [1 ]
Yang, Yanting [1 ]
Liu, Xiaodong [1 ]
Wang, Dongmei [1 ]
Zhang, Xiaomei [2 ]
Zhuo, Linhai [3 ]
机构：
[1] Shandong Univ Sci & Technol, Sch Chem & Environm Engn, Qingdao 266510, Peoples R China
[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Elect Chem, Changchun 130022, Peoples R China
来源：
MATERIALS SCIENCE & ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS | 2013年 / 33卷 / 08期
基金：
中国国家自然科学基金;
关键词：
Porphyrin; Self-assembly; Nanospheres; Temperature dependent; FACILE FABRICATION; IONIC SURFACTANTS; PORPHYRIN; NANOSTRUCTURES; NANOTUBES; NANOPARTICLES; METALLIZATION; ORGANIZATION; FLUORESCENCE; NANOFIBERS;
D O I：
10.1016/j.msec.2013.08.015
中图分类号：
TB3 [工程材料学]; R318.08 [生物材料学];
学科分类号：
0805 ; 080501 ; 080502 ;
摘要：
Various nanostructures of 5,10,15,20-tetrakis(4-carboxyl phenyl)-porphyrin (H2TCPP) can be easily synthesized by a surfactant-assisted self-assembly (SAS) method at different temperatures. When the DMF solution of porphyrin monomer was injected into cetyltimethylammonium bromide (CAB) aqueous solution by a syringe, diverse H2TCPP nanostructures dependent on the different temperatures, including hollow nanospheres, solid nanospheres and nanospheres with holes, were successfully obtained. As a result, the suitable concentration of the CTAB aqueous solution used to form nanostructues of porphyrin ranges from 0.15 to 02 mM. The various morphologies of porphyrin nanostructures were characterized by transmission electron microscopy (TEM), high resolution transmission electron microscopy (HRTEM) and scanning electron microscopy (SEM). UV-vis adsorption spectra showed that the micro-/nano-aggregate properties of porphyrin transformed from H-aggretates to J-aggregates during the process of self-assembly of porphyrin at different temperatures. Fluorescence spectra revealed a greater fluorescence quenching of various micro-/nano-aggregatess of porphyrin formed at different temperatures in aqueous solution, compared to the DMF solution of porphyrin monomer. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：4944 / 4951
页数：8
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