Rhodium-Catalyzed β-Selective Oxidative Heck-Type Coupling of Vinyl Acetate via C-H Activation

被引：34

作者：

Zhang, Hui-Jun ^{[1
]}

Lin, Weidong ^{[1
]}

Su, Feng ^{[1
]}

Wen, Ting-Bin ^{[1
]}

机构：

[1] Xiamen Univ, Dept Chem, Coll Chem & Chem Engn, Xiamen 361005, Fujian, Peoples R China

来源：

ORGANIC LETTERS | 2016年 / 18卷 / 24期

关键词：

UNACTIVATED ALKENES; BOND ACTIVATION; BENZOIC-ACIDS; N-OXIDES; OLEFINATION; ARENES; ALKENYLATION; ARYLATION; ESTERS; FUNCTIONALIZATION;

D O I：

10.1021/acs.orglett.6b03244

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient Rh(III)-catalyzed direct ortho-C-H olefination of acetanilides with vinyl acetate was developed. This protocol provides a straightforward pathway to a series of (E)-2-acetamidostyryl acetates, giving access to indole derivatives following a simple hydrolysis/cyclization process.

引用

页码：6356 / 6359

页数：4

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