Self-Assembly of a Nanoscopic Pt12Fe12 Heterometallic Open Molecular Box Containing Six Porphyrin Walls

被引：151

作者：

Bar, Arun Kumar ^{[1
]}

Chakrabarty, Rajesh ^{[1
]}

Mostafa, Golam ^{[2
]}

Mukherjee, Partha Sarathi ^{[1
]}

机构：

[1] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

[2] Jadavpur Univ, Dept Phys, Kolkata 700032, India

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 44期

关键词：

cluster compounds; coordination modes; N ligands; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200803543

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) Box it up! Self-assembly of 5,10,15,20-tetrakis(4-pyridyl)porphyrin with two equivalents of cis-[(dppf)Pt(OTf)2] (dppf=1,1′-bis(diphenylphosphino) ferrocene; OTf=CF3SO3-) yielded the first open molecular box containing six porphyrin walls (see scheme) and an internal open void volume of around 43550 Å3. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：8455 / 8459

页数：5

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