Perspective: The glass transition

被引:296
作者
Biroli, Giulio [1 ]
Garrahan, Juan P. [2 ]
机构
[1] CEA Saclay, IPhT, CEA DSM CNRS URA 2306, F-91191 Gif Sur Yvette, France
[2] Univ Nottingham, Sch Phys & Astron, Nottingham NG7 2RD, England
基金
英国工程与自然科学研究理事会;
关键词
SPATIALLY HETEROGENEOUS DYNAMICS; SUPERCOOLED O-TERPHENYL; MODE-COUPLING THEORY; FORMING LIQUIDS; STRUCTURAL RELAXATION; MOLECULAR-DYNAMICS; QUANTUM-SYSTEMS; LENGTH SCALES; FIELD-THEORY; TIME SCALES;
D O I
10.1063/1.4795539
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We provide here a brief perspective on the glass transition field. It is an assessment, written from the point of view of theory, of where the field is and where it seems to be heading. We first give an overview of the main phenomenological characteristics, or "stylised facts," of the glass transition problem, i.e., the central observations that a theory of the physics of glass formation should aim to explain in a unified manner. We describe recent developments, with a particular focus on real space properties, including dynamical heterogeneity and facilitation, the search for underlying spatial or structural correlations, and the relation between the thermal glass transition and athermal jamming. We then discuss briefly how competing theories of the glass transition have adapted and evolved to account for such real space issues. We consider in detail two conceptual and methodological approaches put forward recently, that aim to access the fundamental critical phenomenon underlying the glass transition, be it thermodynamic or dynamic in origin, by means of biasing of ensembles, of configurations in the thermodynamic case, or of trajectories in the dynamic case. We end with a short outlook. (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4795539]
引用
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页数:13
相关论文
共 166 条
[31]   Many-body physics with ultracold gases [J].
Bloch, Immanuel ;
Dalibard, Jean ;
Zwerger, Wilhelm .
REVIEWS OF MODERN PHYSICS, 2008, 80 (03) :885-964
[32]   Superglass phase of 4He [J].
Boninsegni, M ;
Prokof'ev, N ;
Svistunov, B .
PHYSICAL REVIEW LETTERS, 2006, 96 (10) :1-4
[33]   On the Adam-Gibbs-Kirkpatrick-Thirumalai-Wolynes scenario for the viscosity increase in glasses [J].
Bouchaud, JP ;
Biroli, G .
JOURNAL OF CHEMICAL PHYSICS, 2004, 121 (15) :7347-7354
[34]   Glass rheology: From mode-coupling theory to a dynamical yield criterion [J].
Brader, Joseph M. ;
Voigtmann, Thomas ;
Fuchs, Matthias ;
Larson, Ronald G. ;
Cates, Michael E. .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2009, 106 (36) :15186-15191
[35]   Geometric interpretation of previtrification in hard sphere liquids [J].
Brito, Carolina ;
Wyart, Matthieu .
JOURNAL OF CHEMICAL PHYSICS, 2009, 131 (02)
[36]   Evidence of Growing Spatial Correlations during the Aging of Glassy Glycerol [J].
Brun, C. ;
Ladieu, F. ;
L'Hote, D. ;
Biroli, G. ;
Bouchaud, J-P. .
PHYSICAL REVIEW LETTERS, 2012, 109 (17)
[37]   Phase-Separation Perspective on Dynamic Heterogeneities in Glass-Forming Liquids [J].
Cammarota, C. ;
Cavagna, A. ;
Giardina, I. ;
Gradenigo, G. ;
Grigera, T. S. ;
Parisi, G. ;
Verrocchio, P. .
PHYSICAL REVIEW LETTERS, 2010, 105 (05)
[38]  
Cammarota C., EUROPHYS LE IN PRESS
[39]  
Cammarota C., J CHEM PHYS IN PRESS
[40]   Ideal glass transitions by random pinning [J].
Cammarota, Chiara ;
Biroli, Giulio .
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2012, 109 (23) :8850-8855