Reduced graphene oxide wrapped hollow molybdenum trioxide nanorod for high performance lithium-ion batteries

被引:16
作者
Yang, Chenglong [1 ]
Zhong, Xiongwu [1 ]
Jiang, Yu [1 ]
Yu, Yan [1 ,2 ]
机构
[1] Univ Sci & Technol China, Chinese Acad Sci, Dept Chem & Mat Sci, Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
[2] Univ Sci & Technol China, State Key Lab Fire Sci, Hefei 230026, Anhui, Peoples R China
基金
中国国家自然科学基金; 国家重点研发计划;
关键词
Lithium-ion batteries; Anode; MoO3; rGO; high performance; METAL-ORGANIC FRAMEWORK; HIGH-CAPACITY; ELECTROCHEMICAL PERFORMANCE; CATHODE MATERIAL; NANOWIRE ARRAYS; RATE CAPABILITY; NANOCOMPOSITE; CARBON; ANODE; MOO3;
D O I
10.1016/j.cclet.2017.11.027
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reduced graphene oxide wrapped hollow molybdenum trioxide nanorods (MoO3@rGO) have been fabricated by a facile process. The MoO3@rGO shows improved lithium storage performance. It could deliver a high reversible capacity (842 mAh/g at 0.1 A/g), excellent cycling stability (778 mAh/g at 0.1 Aig after 200 cycles) and excellent rate capability (455 mAh/g at 2 A/g). The excellent electrochemical performance could be attributed as the special core (MoO3)/sheath (rGO) structure, which could accommodate the volume change of MoO3 during lithiation/delithiation process. In addition, the rGO coating layer could improve the electronic conductivity of MoO3. (C) 2017 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:2231 / 2234
页数:4
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