Novel Assembly of an MoS2 Electrocatalyst onto a Silicon Nanowire Array Electrode to Construct a Photocathode Composed of Elements Abundant on the Earth for Hydrogen Generation

被引：107

作者：

Tran, Phong D. ^{[1
]}

Pramana, Stevin S. ^{[2
]}

Kale, Vinayak S. ^{[1
]}

Mai Nguyen ^{[1
]}

Chiam, Sing Yang ^{[3
]}

Batabyal, Sudip K. ^{[1
]}

Wong, Lydia H. ^{[4
]}

Barber, James ^{[4
,5
]}

Loo, Joachim ^{[4
]}

机构：

[1] Nanyang Technol Univ ERI N, Energy Res Inst, Singapore 637553, Singapore

[2] Nanyang Technol Univ, Facil Anal Chracterizat Testing & Simulat, Singapore 639798, Singapore

[3] ASTAR, Inst Mat Res & Engn, Singapore 117602, Singapore

[4] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore

[5] Univ London Imperial Coll Sci Technol & Med, Div Mol Biosci, London SW7 2AZ, England

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 44期

关键词：

hydrogen; molybdenum; photocatalysis; solar fuels; water splitting; PHOTOCATALYTIC H-2 EVOLUTION; SOLAR;

D O I：

10.1002/chem.201202214

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mild-mannered catalyst: A novel procedure to load a MoS 2 co-catalyst onto the surface of silicon under mild-conditions (room temperature, atmospheric pressure, aqueous solution) by a photo-assisted electrodeposition process employing commercially available precursors is reported. The obtained Si-NW@MoS 2 photocathode showed similar catalytic activity for light-driven H 2 generation compared with a Si-NW@Pt photocathode (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：13994 / 13999

页数：6

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