Synthesis, Structures, and Properties of Thieno[3,2-b]thiophene and Dithiophene Bridged Isoindigo Derivatives and Their Organic Field-effect Transistors Performance

被引：28

作者：

Wu, Ti ^{[1
,2
]}

Yu, Chunmeng ^{[1
,3
]}

Guo, Yunlong ^{[1
]}

Liu, Hongtao ^{[1
,2
]}

Yu, Gui ^{[1
]}

Fang, Yu ^{[3
]}

Liu, Yunqi ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China

[3] Shanxi Normal Univ, MOE, Key Lab Appl Surface & Colloid Chem, Xian 710062, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2012年 / 116卷 / 43期

基金：

中国国家自然科学基金;

关键词：

HIGH-MOBILITY; ANTITUMOR-ACTIVITY; SOLAR-CELLS; POLYMERS; SUBSTITUENTS; BANDGAP;

D O I：

10.1021/jp304697r

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Organic semiconductors (ITTI and IDTI) characterized of thieno[3,2-b]thiophene and dithiophene bridged isoindigo derivatives were designed and successfully synthesized. H-1-C-13 HMBC, (HH)-H-1-H-1 nuclear Overhauser enhancement spectroscopy (NOESY) spectra, and H-1 nuclear Overhauser enhancement (NOE) experiments were employed to determine the configurations of the synthesized molecules, indicating they belong to stable Z,Z configurations. Organic field-effect transistors based on ITTI and IDTI through a solution processed method have good air stabilities and exhibit hole mobilities of 0.045 and 0.075 cm(2) V-1 s(-1) after high-temperature annealing in air, respectively.

引用

页码：22655 / 22662

页数：8

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