Organocatalytic deprotonative functionalization of C(sp2)-H and C(sp3)-H bonds using in situ generated onium amide bases

被引：35
|
作者：
Inamoto, Kiyofumi [1 ]
Okawa, Hitomi [1 ]
Taneda, Hiroshi [1 ]
Sato, Maomi [1 ]
Hirono, Yutaro [1 ]
Yonemoto, Misato [1 ]
Kikkawa, Shoko [1 ]
Kondo, Yoshinori [1 ]
机构：
[1] Tohoku Univ, Grad Sch Pharmaceut Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan
来源：
CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 78期
基金：
日本学术振兴会;
关键词：
C-H BONDS; DIRECTED METALATION; NUCLEOPHILIC TRIFLUOROMETHYLATION; CHEMOSELECTIVE BASE; DIAZINES PYRIDINES; CARBONYL-COMPOUNDS; N-BUTYLLITHIUM; QUINOLINES; ARENES; BENZODIAZINES;
D O I：
10.1039/c2cc35701a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Onium amides, generated in situ from the combination of aminosilanes and onium fluorides (R4PF, R4NF), are employed for the first time as bases for catalytic deprotonative functionalization of C(sp(2))-H and activated C(sp(3))-H bonds under mild conditions.
引用
收藏
页码：9771 / 9773
页数：3
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