CO2 Reforming of CH4 over Co/Oxidized Diamond Catalyst

被引：14

作者：

Nakagawa, Kiyoharu ^{[1
,2
,3
]}

Kikuchi, Mayuko ^{[2
,3
]}

Nishitani-Gamo, Mikka ^{[2
,3
]}

Oda, Hirokazu ^{[4
,5
]}

Ganto, Hidenori ^{[6
]}

Ogawa, Kazuyuki ^{[1
]}

Ando, Toshihiro ^{[1
]}

机构：

[1] Natl Inst Mat Sci, Tsukuba, Ibaraki 3050044, Japan

[2] Toyo Univ, Dept Appl Chem, Kawagoe, Saitama 3508585, Japan

[3] Toyo Univ, Sensor Photon Res Ctr, Kawagoe, Saitama 3508585, Japan

[4] Kansai Univ, Dept Chem Engn, Osaka 5648680, Japan

[5] Kansai Univ, High Technol Res Ctr, Osaka 5648680, Japan

[6] Toppan Printing Co Ltd, Tech Res Inst, Sugito, Saitama 3458508, Japan

来源：

ENERGY & FUELS | 2008年 / 22卷 / 06期

关键词：

D O I：

10.1021/ef800265x

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

We examined synthesis gas (H-2 and CO) production from CO2 reforming of methane using a Co/oxidized diamond catalyst to investigate the properties of oxidized diamond as a support material and as a way to avoid carbon deposition on cobalt-loaded catalysts. Oxidized diamond showed a good catalytic performance among various support materials. No carbon deposition was observed when using the Co/oxidized diamond catalyst in CO2 reforming of CH4. In addition, CH4 conversion was maintained for 10 h during CO2 reforming of CH4 over the Co/oxidized diamond catalyst. In the CO2 reforming of CH4, active cobalt species might be formed or deposited carbon would be rapidly eliminated on oxidized diamond-supported catalyst.

引用

页码：3566 / 3570

页数：5

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